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Oxyborylene als Photoreduktionsmittel: Synthese und Anwendung in Dehalogenierungen und Detosylierungen.
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- Angewandte Chemie, 2022, v. 134, n. 42, p. 1, doi. 10.1002/ange.202209391
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Oxy‐Borylenes as Photoreductants: Synthesis and Application in Dehalogenation and Detosylation Reactions.
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- Angewandte Chemie International Edition, 2022, v. 61, n. 42, p. 1, doi. 10.1002/anie.202209391
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Solid‐State Nuclear Magnetic Resonance Techniques for the Structural Characterization of Geminal Alane‐Phosphane Frustrated Lewis Pairs and Secondary Adducts.
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- Chemistry - A European Journal, 2021, v. 27, n. 52, p. 13249, doi. 10.1002/chem.202102113
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New Reactivity Patterns in 3H‐Phosphaallene Chemistry [Aryl‐P=C=C(H)‐tBu]: Hydroboration of the C=C Bond, Deprotonation and Trimerisation.
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- Chemistry - A European Journal, 2020, v. 26, n. 68, p. 15977, doi. 10.1002/chem.202002506
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Hydrosilylation and Hydrogermylation of CO<sub>2</sub> and CS<sub>2</sub> by Al and Ga Functionalized Silanes and Germanes – Cooperative Reactivity with Formation of Silyl Formates and Disilylacetals.
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- European Journal of Inorganic Chemistry, 2020, v. 2020, n. 42, p. 4024, doi. 10.1002/ejic.202000723
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Reactions of Al‐N Based Active Lewis Pairs with Ketones and 1,2‐Diketones: Insertion into Al‐N Bonds, C‐C and C‐N Bond Formation and a Tricyclic Saturated Tetraaza Compound.
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- European Journal of Inorganic Chemistry, 2020, v. 2020, n. 39, p. 3760, doi. 10.1002/ejic.202000570
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Al/N-based active Lewis pairs: isocyanate insertion products as efficient nucleophiles employed for the facile generation of highly functional molecules.
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- Zeitschrift für Naturforschung B: A Journal of Chemical Sciences, 2020, v. 75, n. 6/7, p. 615, doi. 10.1515/znb-2020-0049
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Al/N-based active Lewis pairs: isocyanate insertion products as efficient nucleophiles employed for the facile generation of highly functional molecules.
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- Zeitschrift für Naturforschung B: A Journal of Chemical Sciences, 2020, v. 75, n. 6, p. 615, doi. 10.1515/znb-2020-0049
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Al/N-based active Lewis pairs: isocyanate insertion products as efficient nucleophiles employed for the facile generation of highly functional molecules.
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- Zeitschrift für Naturforschung B: A Journal of Chemical Sciences, 2020, p. 615, doi. 10.1515/znb-2020-0049
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Cooperative activation of azides by an Al/N-based active Lewis pair – unexpected insertion of nitrogen atoms into C–Si bonds and formation of AlCN<sub>3</sub> heterocycles.
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- Zeitschrift für Naturforschung B: A Journal of Chemical Sciences, 2020, v. 75, n. 1/2, p. 63, doi. 10.1515/znb-2019-0138
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Dihalides of Sterically Constrained Tricyclic Phosphines, Lewis Acidity and Fluoride Affinity, Chloride Abstraction, and a Phosphonium Cation, Dimethylphosphorane.
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- European Journal of Inorganic Chemistry, 2020, v. 2020, n. 4, p. 361, doi. 10.1002/ejic.201901231
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New Ga/N‐based Active Lewis Pairs, Trifunctional Ga–Ga Compounds, Reactions with Cyanamide and Dual Insertion of Isocyanate.
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- Zeitschrift für Anorganische und Allgemeine Chemie, 2019, v. 645, n. 20, p. 1205, doi. 10.1002/zaac.201900195
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Aluminium Functionalized Germanes: Intramolecular Activation of Ge–H Bonds, Formation of a Dihydrogen Bond and Facile Hydrogermylation of Unsaturated Substrates.
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- European Journal of Inorganic Chemistry, 2019, v. 2019, n. 28, p. 3287, doi. 10.1002/ejic.201900543
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Al/P‐ and Ga/P‐Based Frustrated Lewis Pairs and Electronically Unsaturated Substrates: Ring Cleavage and Ring Closure, C−C and C−N Bond Formation.
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- Chemistry - A European Journal, 2019, v. 25, n. 39, p. 9315, doi. 10.1002/chem.201901659
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3H‐Phosphaallenes Revisited: Facile Synthesis by Hydroalumination of Alkynylphosphines and β‐Elimination, Stability and Trapping of Transient Species by Coordination to Transition Metal Atoms.
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- Chemistry - A European Journal, 2019, v. 25, n. 18, p. 4793, doi. 10.1002/chem.201806334
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Silicon–Halogen Bond Activation in Mixed Si/Al Compounds and an Approach to Intramolecular Stabilized Silylium Ions.
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- European Journal of Inorganic Chemistry, 2019, v. 2019, n. 5, p. 693, doi. 10.1002/ejic.201801273
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Sterically Constrained Bicyclic Phosphines: A Class of Fascinating Compounds Suitable for Application in Small Molecule Activation and Coordination Chemistry.
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- Chemistry - A European Journal, 2019, v. 25, n. 6, p. 1391, doi. 10.1002/chem.201803331
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Supramolecular Chemistry Based on Frustrated Lewis Pairs – Reactions of an Al/P FLP with Potassium Formate and Cesium Fluoride.
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- Zeitschrift für Anorganische und Allgemeine Chemie, 2018, v. 644, n. 22, p. 1469, doi. 10.1002/zaac.201800256
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Hydroalumination of Oligoalkynylgermanes and ‐digermanes – Reactions with Heterocumulenes by Al–C or Ge–C Bond Activation and Formation of a Hexazenedialuminum Complex.
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- Zeitschrift für Anorganische und Allgemeine Chemie, 2018, v. 644, n. 17, p. 945, doi. 10.1002/zaac.201800159
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Reactions of an Aluminium/Phosphorus Frustrated Lewis Pair (FLP) with α,β‐Unsaturated Carbonyl Compounds: FLPs as Efficient Two‐Electron Reductants with the Formation of Enolates, a cis‐Enediolate, and an Allene.
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- Chemistry - A European Journal, 2018, v. 24, n. 49, p. 12856, doi. 10.1002/chem.201706089
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Ein gespanntes tricyclisches PC<sub>3</sub>‐Phosphan – Koordinationschemie und Insertion von Chalkogenatomen in P‐C‐Bindungen.
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- Angewandte Chemie, 2018, v. 130, n. 3, p. 840, doi. 10.1002/ange.201711373
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A Sterically Constrained Tricyclic PC<sub>3</sub> Phosphine: Coordination Behavior and Insertion of Chalcogen Atoms into P−C Bonds.
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- Angewandte Chemie International Edition, 2018, v. 57, n. 3, p. 832, doi. 10.1002/anie.201711373
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Reactivity of a P--H Functionalized Al/P-Based Frustrated Lewis Pair - Hydrophosphination versus Classic Adduct Formation.
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- Zeitschrift für Anorganische und Allgemeine Chemie, 2017, v. 643, n. 23, p. 1978, doi. 10.1002/zaac.201700340
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Reactions of Al/P, Ga/P and P-H functionalized frustrated Lewis pairs with azides and a diazomethane -- formation of adducts and capture of nitrenes.
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- Zeitschrift für Naturforschung B: A Journal of Chemical Sciences, 2017, v. 72, n. 11, p. 821, doi. 10.1515/znb-2017-0099
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Reactions of a Ga/P-Based Frustrated Lewis Pair with HX (X = F - I), Heterocumulenes R-NCY (Y = O, S) and Chalcogens-Adduct Formation and Surprising Stability towards Protolysis.
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- Zeitschrift für Anorganische und Allgemeine Chemie, 2017, v. 643, n. 15, p. 1016, doi. 10.1002/zaac.201700146
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Gerd Becker (1940-2017).
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- Angewandte Chemie, 2017, v. 129, n. 23, p. 6472, doi. 10.1002/ange.201703696
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Gerd Becker (1940-2017).
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- Angewandte Chemie International Edition, 2017, v. 56, n. 23, p. 6374, doi. 10.1002/anie.201703696
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Cooperative Activation of Isocyanates by Al-N-Based Active Lewis Pairs and the Generation of a C<sub>5</sub> Chain by Simultaneous Formation of Two C-C Bonds.
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- Chemistry - A European Journal, 2017, v. 23, n. 25, p. 6129, doi. 10.1002/chem.201604630
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Einfache Modulierung von FLP-Eigenschaften: ein Phosphanylvinyl-Grignard-Reagenz und Ga/P- oder In/P<sub>2</sub>-basierte frustrierte Lewis-Paare.
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- Angewandte Chemie, 2017, v. 129, n. 11, p. 3140, doi. 10.1002/ange.201612485
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Facile Modulation of FLP Properties: A Phosphinylvinyl Grignard Reagent and Ga/P- and In/P<sub>2</sub>-Based Frustrated Lewis Pairs.
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- Angewandte Chemie International Edition, 2017, v. 56, n. 11, p. 3094, doi. 10.1002/anie.201612485
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A Dimeric Gallium Hydrazide as an Active Lewis Pair - Complexation and Activation of Me<sub>2</sub>GaH and Various Heterocumulenes.
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- Zeitschrift für Anorganische und Allgemeine Chemie, 2017, v. 643, n. 5, p. 387, doi. 10.1002/zaac.201600456
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Reaction of an Al/P-based frustrated Lewis pair with benzophenone: formation of adducts and aluminium alcoholates via β-hydride elimination.
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- Zeitschrift für Naturforschung B: A Journal of Chemical Sciences, 2016, v. 71, n. 10, p. 1043, doi. 10.1515/znb-2016-0118
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σ-Bond Activation in Aluminium-Functionalized Alkynylchlorogermanes: Facile Insertion of Isocyanate and Azide into Al-C and Ge-Cl Bonds.
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- European Journal of Inorganic Chemistry, 2016, v. 2016, n. 26, p. 4170, doi. 10.1002/ejic.201600764
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Reactivity of a Monomeric Aluminium Hydrazide towards Isocyanates and Isothiocyanates: Active Lewis Pair Behaviour versus Classical Insertion Reactions.
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- European Journal of Inorganic Chemistry, 2016, v. 2016, n. 17, p. 2721, doi. 10.1002/ejic.201600170
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Hydroalumination and hydrogallation of an aryl-chloro-dialkynylsilane: Si-Cl bond activation by intramolecular Al-Cl and Ga-Cl interactions.
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- Zeitschrift für Naturforschung B: A Journal of Chemical Sciences, 2016, v. 71, n. 5, p. 509, doi. 10.1515/znb-2016-0004
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Ein P-H-funktionalisiertes Al/P-basiertes frustriertes Lewis-Paar: Substrataktivierung und selektiver Wasserstofftransfer.
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- Angewandte Chemie, 2016, v. 128, n. 9, p. 3266, doi. 10.1002/ange.201511048
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A P−H Functionalized Al/P Frustrated Lewis Pair: Substrate Activation and Selective Hydrogen Transfer.
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- Angewandte Chemie International Edition, 2016, v. 55, n. 9, p. 3212, doi. 10.1002/anie.201511048
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Dehydrochlorination of Carboxylic Acid Chlorides by an Aluminum/Phosphorus-Based Frustrated Lewis Pair and the Formation of Ketene Adducts.
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- Zeitschrift für Anorganische und Allgemeine Chemie, 2015, v. 641, n. 12/13, p. 2102, doi. 10.1002/zaac.201500519
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Heterocyclic Digallanates, Encapsulation of Lithium Cations in Organometallic Cages and C-H Bond Activation.
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- European Journal of Inorganic Chemistry, 2015, v. 2015, n. 14, p. 2486, doi. 10.1002/ejic.201500207
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Germacyclobutenes: Generation by 1,1-Carbalumination or 1,1-Carbagallation and Their Photophysical Properties.
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- Chemistry - A European Journal, 2015, v. 21, n. 6, p. 2629, doi. 10.1002/chem.201405739
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Cooperative GeN Bond Activation in Aluminium-Functionalised Aminogermanes and Spontaneous Imine Elimination via an Intermediate Germyl Cation.
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- Chemistry - A European Journal, 2015, v. 21, n. 6, p. 2638, doi. 10.1002/chem.201405989
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Supramolecular Chemistry Based on Gallium-Gallium Single Bonds - Formation of Large Heterocycles and Cages with up to Twelve Gallium Atoms.
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- Zeitschrift für Anorganische und Allgemeine Chemie, 2015, v. 641, n. 2, p. 253, doi. 10.1002/zaac.201400517
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Surprising Stability of an Al/P-Based Frustrated Lewis-Pair Towards Protolysis: HX Adducts (X = F, Cl) with Intramolecular H···X Hydrogen Bonds.
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- Zeitschrift für Anorganische und Allgemeine Chemie, 2015, v. 641, n. 2, p. 311, doi. 10.1002/zaac.201400527
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Hydrometallation of amino-dialkynylgermanes – a gallium hydride oligomer and intramolecular Lewis acid-base interactions.
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- Zeitschrift für Naturforschung B: A Journal of Chemical Sciences, 2015, v. 70, n. 2, p. 115, doi. 10.1515/znb-2014-0221
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Dative Au→Al Interactions: Crystallographic Characterization and Computational Analysis.
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- Chemistry - A European Journal, 2015, v. 21, n. 1, p. 74, doi. 10.1002/chem.201405610
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Synthesis and Molecular Structure of a Dimeric Organometallic Indiumsubfluoride.
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- Zeitschrift für Anorganische und Allgemeine Chemie, 2014, v. 640, n. 14, p. 2830, doi. 10.1002/zaac.201400350
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Treatment of the Digallium Compound R<sub>2</sub>Ga-GaR<sub>2</sub> [R = CH(SiMe<sub>3</sub>)<sub>2</sub>] with Functionalized Dicarboxylic Acids: Macrocycles, Hydrogen Bonding, and Sulfur-Sulfur Closed-Shell Interactions.
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- European Journal of Inorganic Chemistry, 2014, v. 2014, n. 22, p. 3521, doi. 10.1002/ejic.201402172
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Hydroalumination of a Chlorotrialkynylsilane: Spontaneous Stepwise 1,3-Dyotropic Rearrangement via an Intermediate Silyl Cation.
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- Chemistry - A European Journal, 2014, v. 20, n. 28, p. 8771, doi. 10.1002/chem.201402713
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Alkenyl-Alkynylgermanes Functionalised by Lewis Acids: Intramolecular Aluminium- and Gallium-Alkyne Interactions and Potential Ge-C Bond Activation.
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- European Journal of Inorganic Chemistry, 2014, v. 2014, n. 17, p. 2809, doi. 10.1002/ejic.201402132
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Molecular Structures of Dimeric and Trimeric Dineopentylaluminum Hydride and Trimeric Diphenylaluminum Hydride.
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- Zeitschrift für Anorganische und Allgemeine Chemie, 2014, v. 640, n. 1, p. 106, doi. 10.1002/zaac.201300484
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