Works by Togni, Antonio

Results: 118

A Simple Manganese(I) Catalyst for the Efficient and Selective Hydrophosphination of Olefins with PH3, Primary, and Secondary Phosphanes.

Published in:

Chemistry - A European Journal, 2024, v. 30, n. 20, p. 1, doi. 10.1002/chem.202303848

By:

Wani, Aabid A.;
Carballo, Juan José Gamboa;
Jayaprakash, Harikrishnan;
Wörle, Michael;
Widera, Anna;
Togni, Antonio;
Grützmacher, Hansjörg

Publication type:

Article

Hydroamination of Triisopropylsilyl Acetylene Sulfur Pentafluoride – a Bench‐top Route to Pentafluorosulfanylated Enamines.

Published in:

Chemistry - A European Journal, 2024, v. 30, n. 14, p. 1, doi. 10.1002/chem.202304015

By:

Wenzel, Jonas O.;
Jester, Fabian;
Togni, Antonio;
Rombach, David

Publication type:

Article

Recyclable Mn(I) Catalysts for Base‐Free Asymmetric Hydrogenation: Mechanistic, DFT and Catalytic Studies.

Published in:

Chemistry - A European Journal, 2022, v. 28, n. 47, p. 1, doi. 10.1002/chem.202201522

By:

Jayaprakash, Harikrishnan;
Coburger, Peter;
Wörle, Michael;
Togni, Antonio;
Grützmacher, Hansjorg

Publication type:

Article

Direkte elektrophile N-Trifluormethylierung von Azolen mit einem hypervalenten Iodreagens.

Published in:

Angewandte Chemie, 2012, v. 124, n. 26, p. 6617, doi. 10.1002/ange.201201572

By:

Niedermann, Katrin;
Früh, Natalja;
Senn, Remo;
Czarniecki, Barbara;
Verel, René;
Togni, Antonio

Publication type:

Article

Eine Ritter-Reaktion: direkte elektrophile Trifluormethylierung von Stickstoffzentren mit hypervalenten Iodreagentien.

Published in:

Angewandte Chemie, 2011, v. 123, n. 5, p. 1091, doi. 10.1002/ange.201006021

By:

Niedermann, Katrin;
Früh, Natalja;
Vinogradova, Ekaterina;
Wiehn, Matthias S.;
Moreno, Aitor;
Togni, Antonio

Publication type:

Article

Cooperativity of chirality in homogeneous catalysis: The gold(I)-catalyzed aldol reaction and the vanadium(IV)-catalyzed hetero Diels-Alder cycloaddition.

Published in:

Chirality, 1991, v. 3, n. 4, p. 331, doi. 10.1002/chir.530030419

By:

Togni, Antonio;
Pastor, Stephen D.

Publication type:

Article

Oxidative Fluorination of Heteroatoms Enabled by Trichloroisocyanuric Acid and Potassium Fluoride.

Published in:

Angewandte Chemie International Edition, 2022, v. 61, n. 31, p. 1, doi. 10.1002/anie.202205088

By:

Kraemer, Yannick;
Bergman, Emily Nicole;
Togni, Antonio;
Pitts, Cody Ross

Publication type:

Article

Deoxygenative Fluorination of Phosphine Oxides: A General Route to Fluorinated Organophosphorus(V) Compounds and Beyond.

Published in:

Angewandte Chemie International Edition, 2020, v. 59, n. 50, p. 22790, doi. 10.1002/anie.202010943

By:

Bornemann, Dustin;
Pitts, Cody Ross;
Wettstein, Lionel;
Brüning, Fabian;
Küng, Sebastian;
Guan, Liangyu;
Trapp, Nils;
Grützmacher, Hansjörg;
Togni, Antonio

Publication type:

Article

Pyridinium Salts as Redox‐Active Functional Group Transfer Reagents.

Published in:

Angewandte Chemie International Edition, 2020, v. 59, n. 24, p. 9264, doi. 10.1002/anie.201911660

By:

Rössler, Simon L.;
Jelier, Benson J.;
Magnier, Emmanuel;
Dagousset, Guillaume;
Carreira, Erick M.;
Togni, Antonio

Publication type:

Article

Difluoro(aryl)(perfluoroalkyl)‐λ4‐sulfanes and Selanes: Missing Links of Trichloroisocyanuric Acid/Potassium Fluoride Chemistry.

Published in:

Angewandte Chemie International Edition, 2019, v. 58, n. 52, p. 18937, doi. 10.1002/anie.201910594

By:

Brüning, Fabian;
Pitts, Cody Ross;
Kalim, Jorna;
Bornemann, Dustin;
Ghiazza, Clément;
Montmollin, Jean;
Trapp, Nils;
Billard, Thierry;
Togni, Antonio

Publication type:

Article

Pentafluoro(aryl)‐λ6‐tellanes and Tetrafluoro(aryl)(trifluoromethyl)‐λ6‐tellanes: From SF5 to the TeF5 and TeF4CF3 Groups.

Published in:

Angewandte Chemie International Edition, 2019, v. 58, n. 36, p. 12604, doi. 10.1002/anie.201907359

By:

Bornemann, Dustin;
Pitts, Cody Ross;
Ziegler, Carmen J.;
Pietrasiak, Ewa;
Trapp, Nils;
Kueng, Sebastian;
Santschi, Nico;
Togni, Antonio

Publication type:

Article

Facile and Efficient Synthesis of 3‐Pyrimidinyl Oxindoles by Phase‐Transfer‐Catalyzed Regioselective Nucleophilic Aromatic Substitution.

Published in:

European Journal of Organic Chemistry, 2018, v. 2018, n. 31, p. 4256, doi. 10.1002/ejoc.201800587

By:

Brüning, Fabian;
Katayev, Dmitry;
Togni, Antonio

Publication type:

Article

Supramolecular Aggregation of Perfluoroorganyl Iodane Reagents in the Solid State and in Solution.

Published in:

European Journal of Organic Chemistry, 2018, v. 2018, n. 27/28, p. 3771, doi. 10.1002/ejoc.201800358

By:

Liebing, Phil;
Pietrasiak, Ewa;
Otth, Elisabeth;
Kalim, Jorna;
Bornemann, Dustin;
Togni, Antonio

Publication type:

Article

On the Effect of Backbone Modifications in 3,3-Dimethyl-1-(trifluoromethyl)-3 H-1λ3,2-benziodaoxole.

Published in:

European Journal of Organic Chemistry, 2015, v. 2015, n. 9, p. 1925, doi. 10.1002/ejoc.201403634

By:

Santschi, Nico;
Matthey, Coraline;
Schwenk, Rino;
Otth, Elisabeth;
Togni, Antonio

Publication type:

Article

On the Effect of Backbone Modifications in 3,3-Dimethyl-1-(trifluoromethyl)-3 H-1λ3,2-benziodaoxole (Eur. J. Org. Chem. 9/2015).

Published in:

European Journal of Organic Chemistry, 2015, v. 2015, n. 9, p. n/a, doi. 10.1002/ejoc.201403634

By:

Santschi, Nico;
Matthey, Coraline;
Schwenk, Rino;
Otth, Elisabeth;
Togni, Antonio

Publication type:

Article

Rapid and Selective Electrophilic Trifluoromethylation of the 4,4-Difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) Scaffold.

Published in:

European Journal of Organic Chemistry, 2014, v. 2014, n. 29, p. 6371, doi. 10.1002/ejoc.201402874

By:

Santschi, Nico;
Cvengroš, Ján;
Matthey, Coraline;
Otth, Elisabeth;
Antonio Togni, and

Publication type:

Article

O-Trifluoromethylation of N, N-Disubstituted Hydroxylamines with Hypervalent Iodine Reagents.

Published in:

European Journal of Organic Chemistry, 2014, v. 2014, n. 15, p. 3087, doi. 10.1002/ejoc.201402225

By:

Matoušek, Václav;
Pietrasiak, Ewa;
Sigrist, Lukas;
Czarniecki, Barbara;
Togni, Antonio

Publication type:

Article

New Tungsten-Iridium Dinuclear Complexes Containing Cyclopentadienyl and Hydrido Bridges.

Published in:

Angewandte Chemie International Edition, 1981, v. 20, n. 8, p. 668, doi. 10.1002/anie.198106682

By:

Pregosin, Paul S.;
Togni, Antonio;
Venanzi, Luigi M.

Publication type:

Article

Asymmetric Transfer Hydrogenation of Ketones Catalyzed by Rhenium Complexes with Chiral Ferrocenylphosphane Ligands.

Published in:

European Journal of Inorganic Chemistry, 2012, v. 2012, n. 31, p. 5021, doi. 10.1002/ejic.201200693

By:

Mejía, Esteban;
Aardoom, Raphael;
Togni, Antonio

Publication type:

Article

Interactions of Cationic Palladium(II)- and Platinum(II)-η3-Allyl Complexes with Fluoride: Is Asymmetric Allylic Fluorination a Viable Reaction?

Published in:

European Journal of Inorganic Chemistry, 2006, v. 2006, n. 7, p. 1397

By:

Lukas Hintermann;
Florian Läng;
Pascal Maire;
Antonio Togni

Publication type:

Article

PdII Complexes of Tridentate PCP N-Heterocyclic Carbene Ligands: Structural Aspects and Application in Asymmetric Hydroamination of Cyano Olefins.

Published in:

European Journal of Inorganic Chemistry, 2005, v. 2005, n. 23, p. 4745

By:

Sebastian Gischig;
Antonio Togni

Publication type:

Article

Ruthenium(II) Complexes with Triphosphane Ligands Combining Planar, Phosphorus, and Carbon Chirality: Application to Asymmetric Reduction of Trifluoroacetophenone.

Published in:

European Journal of Inorganic Chemistry, 2003, v. 2003, n. 23, p. 4166

By:

Pierluigi Barbaro;
Claudio Bianchini;
Giuliano Giambastiani;
Antonio Togni

Publication type:

Article

A Tunable Trifluoromethyliodonium Reagent.

Published in:

Angewandte Chemie International Edition, 2019, v. 58, n. 25, p. 8585, doi. 10.1002/anie.201903623

By:

Liebing, Phil;
Kalim, Jorna;
Arefyeva, Natalia;
Oehler, Florian;
Wickleder, Mathias;
Togni, Antonio

Publication type:

Article

Making the SF5 Group More Accessible: A Gas‐Reagent‐Free Approach to Aryl Tetrafluoro‐λ6‐sulfanyl Chlorides.

Published in:

Angewandte Chemie International Edition, 2019, v. 58, n. 7, p. 1950, doi. 10.1002/anie.201812356

By:

Pitts, Cody Ross;
Bornemann, Dustin;
Liebing, Phil;
Santschi, Nico;
Togni, Antonio

Publication type:

Article

Taming Radical Intermediates for the Construction of Enantioenriched Trifluoromethylated Quaternary Carbon Centers.

Published in:

Angewandte Chemie International Edition, 2019, v. 58, n. 5, p. 1447, doi. 10.1002/anie.201812793

By:

Calvo, Roxan;
Comas‐Vives, Aleix;
Togni, Antonio;
Katayev, Dmitry

Publication type:

Article

Pyridyl Radical Cation for C−H Amination of Arenes.

Published in:

Angewandte Chemie International Edition, 2019, v. 58, n. 2, p. 526, doi. 10.1002/anie.201810261

By:

Rössler, Simon L.;
Jelier, Benson J.;
Tripet, Pascal F.;
Shemet, Andrej;
Jeschke, Gunnar;
Togni, Antonio;
Carreira, Erick M.

Publication type:

Article

Radical Trifluoromethoxylation of Arenes Triggered by a Visible‐Light‐Mediated N−O Bond Redox Fragmentation.

Published in:

Angewandte Chemie International Edition, 2018, v. 57, n. 42, p. 13784, doi. 10.1002/anie.201806296

By:

Jelier, Benson J.;
Tripet, Pascal F.;
Pietrasiak, Ewa;
Franzoni, Ivan;
Jeschke, Gunnar;
Togni, Antonio

Publication type:

Article

Cover Picture: Exposing the Origins of Irreproducibility in Fluorine NMR Spectroscopy (Angew. Chem. Int. Ed. 30/2018).

Published in:

2018

By:

Rosenau, Carl Philipp;
Jelier, Benson J.;
Gossert, Alvar D.;
Togni, Antonio

Publication type:

Cover Art

Exposing the Origins of Irreproducibility in Fluorine NMR Spectroscopy.

Published in:

Angewandte Chemie International Edition, 2018, v. 57, n. 30, p. 9528, doi. 10.1002/anie.201802620

By:

Rosenau, Carl Philipp;
Jelier, Benson J.;
Gossert, Alvar D.;
Togni, Antonio

Publication type:

Article

Vanadium-Catalyzed Solvent-Free Synthesis of Quaternary α-Trifluoromethyl Nitriles by Electrophilic Trifluoromethylation.

Published in:

Angewandte Chemie International Edition, 2014, v. 53, n. 40, p. 10813, doi. 10.1002/anie.201406181

By:

Früh, Natalja;
Togni, Antonio

Publication type:

Article

Development and Molecular Understanding of a Pd‐Catalyzed Cyanation of Aryl Boronic Acids Enabled by High‐Throughput Experimentation and Data Analysis.

Published in:

Helvetica Chimica Acta, 2021, v. 104, n. 12, p. 1, doi. 10.1002/hlca.202100200

By:

De Jesus Silva, Jordan;
Bartalucci, Niccolò;
Jelier, Benson;
Grosslight, Samantha;
Gensch, Tobias;
Schünemann, Claas;
Müller, Bernd;
Kamer, Paul C. J.;
Copéret, Christophe;
Sigman, Matthew S.;
Togni, Antonio

Publication type:

Article

Acrylate Esters by Ethenolysis of Maleate Esters with Ru Metathesis Catalysts: an HTE and a Technoeconomic Study.

Published in:

Helvetica Chimica Acta, 2020, v. 103, n. 4, p. 1, doi. 10.1002/hlca.202000035

By:

Engl, Pascal S.;
Tsygankov, Alexey;
De Jesus Silva, Jordan;
Lange, Jean‐Paul;
Copéret, Christophe;
Togni, Antonio;
Fedorov, Alexey

Publication type:

Article

Trifluoromethyl Derivatives of Benzooxatellurole.

Published in:

Helvetica Chimica Acta, 2019, v. 102, n. 6, p. N.PAG, doi. 10.1002/hlca.201900079

By:

Pietrasiak, Ewa;
Baxter, Amanda F.;
Jelier, Benson;
Santschi, Nico;
Togni, Antonio

Publication type:

Article

Hypervalent Iodine Reagents: Thiol Derivatization with a Tetrafluoroethoxy Coumarin Residue for UV Absorbance Recognition.

Published in:

Helvetica Chimica Acta, 2017, v. 100, n. 5, p. n/a, doi. 10.1002/hlca.201700059

By:

Commare, Bruno;
Togni, Antonio

Publication type:

Article

Planar-Chiral Ferrocenes: Synthetic Methods and Applications.

Published in:

Angewandte Chemie International Edition, 1996, v. 35, n. 13/14, p. 1475, doi. 10.1002/anie.199614751

By:

Togni, Antonio

Publication type:

Article

Strong Electronic Effects on Enantioselectivity in Rhodium-Catalyzed Hydroborations with Novel Pyrazole-Containing Ferrocenyl Ligands.

Published in:

Angewandte Chemie International Edition, 1995, v. 34, n. 8, p. 931, doi. 10.1002/anie.199509311

By:

Schnyder, Anita;
Hintermann, Lukas;
Togni, Antonio

Publication type:

Article

Nitrogen Donors in Organometallic Chemistry and Homogeneous Catalysis.

Published in:

Angewandte Chemie International Edition, 1994, v. 33, n. 5, p. 497, doi. 10.1002/anie.199404971

By:

Togni, Antonio;
Venanzi, Luigi M.

Publication type:

Article

Structure of Chloro(cyclopentadienyl)bis(1,2:5,6-di- O-isopropylidene-α- D-glucofuranos-3-O-yl) Titanate, a Novel Titanium-Carbohydrate Complex.

Published in:

Angewandte Chemie International Edition, 1989, v. 28, n. 4, p. 499, doi. 10.1002/anie.198904991

By:

Riediker, Martin;
Hafner, Andreas;
Piantini, Umberto;
Rihs, Grety;
Togni, Antonio

Publication type:

Article

A New Type of Sandwich Complex Formed by Ag1 and [Pt3(μ2-CO)3(P iPr3)3].

Published in:

Angewandte Chemie International Edition, 1985, v. 24, n. 9, p. 766, doi. 10.1002/anie.198507661

By:

Albinati, Alberto;
Dahmen, Klaus-Hermann;
Togni, Antonio;
Venanzi, Luigi M.

Publication type:

Article

Synthesis, characterization, and application in asymmetric catalysis of dendrimers containing chiral ferrocenyl diphosphines.

Published in:

Canadian Journal of Chemistry, 2001, v. 79, n. 11, p. 1762

By:

Köllner, Christoph;
Togni, Antonio

Publication type:

Article

Iridium–Imine and –Amine Complexes Relevant to the (S)-Metolachlor Process: Structures, Exchange Kinetics, and C—H Activation by IrI Causing RacemizationPart II. Part I: see ref. 9. The experimental part of this work was carried out at ETH Zürich.

Published in:

Chemistry - A European Journal, 2004, v. 10, n. 18, p. 4546, doi. 10.1002/chem.200306008

By:

Romano Dorta;
Diego Broggini;
Reinhard Kissner;
Antonio Togni

Publication type:

Article

Chiral Xyliphos Complexes for the Catalytic Imine Hydrogenation Leading to the Metolachlor Herbicide: Isolation of CatalystSubstrate Adducts ( The major part of this work was carried out by R.D. at ETH (ETH Diss. No. 12739). ).

Published in:

Chemistry - A European Journal, 2004, v. 10, n. 6, p. 1312, doi. 10.1002/chem.200490019

By:

Romano Dorta;
Diego Broggini;
Robert Stoop;
Heinz Rüegger;
Felix Spindler;
Antonio Togni

Publication type:

Article

Chiral Xyliphos Complexes for the Catalytic Imine Hydrogenation Leading to the Metolachlor Herbicide: Isolation of CatalystSubstrate Adducts ( The major part of this work was carried out by R.D. at ETH (ETH Diss. No. 12739). ).

Published in:

Chemistry - A European Journal, 2004, v. 10, n. 1, p. 267, doi. 10.1002/chem.200305218

By:

Romano Dorta;
Diego Broggini;
Robert Stoop;
Heinz Rüegger;
Felix Spindler;
Antonio Togni

Publication type:

Article

Pentafluor(aryl)‐λ6‐tellane und Tetrafluor(aryl)(trifluormethyl)‐λ6‐tellane: von SF5‐ zu den TeF5‐ und TeF4CF3‐Gruppen.

Published in:

Angewandte Chemie, 2019, v. 131, n. 36, p. 12734, doi. 10.1002/ange.201907359

By:

Bornemann, Dustin;
Pitts, Cody Ross;
Ziegler, Carmen J.;
Pietrasiak, Ewa;
Trapp, Nils;
Küng, Sebastian;
Santschi, Nico;
Togni, Antonio

Publication type:

Article

Ein abstimmbares Trifluormethyliodonium‐Reagenz.

Published in:

Angewandte Chemie, 2019, v. 131, n. 25, p. 8675, doi. 10.1002/ange.201903623

By:

Liebing, Phil;
Kalim, Jorna;
Arefyeva, Natalia;
Oehler, Florian;
Wickleder, Mathias;
Togni, Antonio

Publication type:

Article

Die SF5‐Gruppe zugänglicher gemacht: Eine gasfreie Synthese von Aryl‐Tetrafluor‐λ6‐Sulfanyl‐Chloriden.

Published in:

Angewandte Chemie, 2019, v. 131, n. 7, p. 1970, doi. 10.1002/ange.201812356

By:

Pitts, Cody Ross;
Bornemann, Dustin;
Liebing, Phil;
Santschi, Nico;
Togni, Antonio

Publication type:

Article

Taming Radical Intermediates for the Construction of Enantioenriched Trifluoromethylated Quaternary Carbon Centers.

Published in:

Angewandte Chemie, 2019, v. 131, n. 5, p. 1461, doi. 10.1002/ange.201812793

By:

Calvo, Roxan;
Comas‐Vives, Aleix;
Togni, Antonio;
Katayev, Dmitry

Publication type:

Article

Pyridyl Radical Cation for C−H Amination of Arenes.

Published in:

Angewandte Chemie, 2019, v. 131, n. 2, p. 536, doi. 10.1002/ange.201810261

By:

Rössler, Simon L.;
Jelier, Benson J.;
Tripet, Pascal F.;
Shemet, Andrej;
Jeschke, Gunnar;
Togni, Antonio;
Carreira, Erick M.

Publication type:

Article

Radikalische Trifluormethoxylierung aromatischer Verbindungen durch photochemische N‐O‐Bindungsaktivierung.

Published in:

Angewandte Chemie, 2018, v. 130, n. 42, p. 13980, doi. 10.1002/ange.201806296

By:

Jelier, Benson J.;
Tripet, Pascal F.;
Pietrasiak, Ewa;
Franzoni, Ivan;
Jeschke, Gunnar;
Togni, Antonio

Publication type:

Article

Titelbild: Fluor‐NMR‐Spektroskopie rekalibriert (Angew. Chem. 30/2018).

Published in:

Angewandte Chemie, 2018, v. 130, n. 30, p. 9329, doi. 10.1002/ange.201805557

By:

Rosenau, Carl Philipp;
Jelier, Benson J.;
Gossert, Alvar D.;
Togni, Antonio

Publication type:

Article