Works by Stephan, Douglas W.

Results: 191

Frustrated Lewis Pairs for Metal-free Hydrogenation Catalysis.

Published in:

Johnson Matthey Technology Review, 2025, v. 69, n. 3, p. 378, doi. 10.1595/205651325X17313449269327

By:

Stephan, Douglas W.

Publication type:

Article

Metal-free Catalytic Olefin Hydrogenation: Low-Temperature H2 Activation by Frustrated Lewis Pairs.

Published in:

Angewandte Chemie, 2012, v. 124, n. 40, p. 10311, doi. 10.1002/ange.201204007

By:

Greb, Lutz;
Oña-Burgos, Pascual;
Schirmer, Birgitta;
Grimme, Stefan;
Stephan, Douglas W.;
Paradies, Jan

Publication type:

Article

H2 Activation and Hydride Transfer to Olefins by Al(C6F5)3-Based Frustrated Lewis Pairs.

Published in:

Angewandte Chemie, 2012, v. 124, n. 33, p. 8397, doi. 10.1002/ange.201203362

By:

Ménard, Gabriel;
Stephan, Douglas W.

Publication type:

Article

Phosphorus as a Lewis Acid: CO2 Sequestration with Amidophosphoranes.

Published in:

Angewandte Chemie, 2012, v. 124, n. 19, p. 4792, doi. 10.1002/ange.201201422

By:

Hounjet, Lindsay J.;
Caputo, Christopher B.;
Stephan, Douglas W.

Publication type:

Article

CH Activation of Isobutylene Using Frustrated Lewis Pairs: Aluminum and Boron σ-Allyl Complexes.

Published in:

Angewandte Chemie, 2012, v. 124, n. 18, p. 4485, doi. 10.1002/ange.201200328

By:

Ménard, Gabriel;
Stephan, Douglas W.

Publication type:

Article

Stoichiometric Reduction of CO2 to CO by Aluminum-Based Frustrated Lewis Pairs.

Published in:

Angewandte Chemie, 2011, v. 123, n. 36, p. 8546, doi. 10.1002/ange.201103600

By:

Ménard, Gabriel;
Stephan, Douglas W.

Publication type:

Article

Frustrierte Lewis-Paare: metallfreie Wasserstoffaktivierung und mehr.

Published in:

Angewandte Chemie, 2010, v. 122, n. 1, p. 50, doi. 10.1002/ange.200903708

By:

Stephan, Douglas W.;
Erker, Gerhard

Publication type:

Article

Frustrated Lewis pairs: A metal-free landmark.

Published in:

Nature Chemistry, 2014, v. 6, n. 11, p. 952, doi. 10.1038/nchem.2093

By:

Stephan, Douglas W.

Publication type:

Article

Copolymerization of sterically demanding phosphine-olefins and 1-hexene.

Published in:

Canadian Journal of Chemistry, 2009, v. 87, n. 11, p. 1620, doi. 10.1139/V09-120

By:

McCahill, Jenny S.J.;
Stephan, Douglas W.

Publication type:

Article

Hafnium–phosphinimide complexes.

Published in:

Canadian Journal of Chemistry, 2009, v. 87, n. 8, p. 1163, doi. 10.1139/V09-082

By:

Alhomaidan, Osamah;
Welch, Gregory C.;
Guangcai Bai;
Stephan, Douglas W.

Publication type:

Article

Aluminum pentafluorophenyl–amide complexes.

Published in:

Canadian Journal of Chemistry, 2007, v. 85, n. 2, p. 135, doi. 10.1139/V07-003

By:

Cornelissen, Carsten;
Chan, Gigi;
Masuda, Jason D.;
Stephan, Douglas W.

Publication type:

Article

Monometallic, homo-, and hetero-bimetallic complexes of a siloxy-bis(phosphinimide) ligand.

Published in:

Canadian Journal of Chemistry, 2006, v. 84, n. 9, p. 1180, doi. 10.1139/V06-148

By:

Martinez, Gema;
Stephan, Douglas W.

Publication type:

Article

Titanium pyridyl-phosphinimide complexes Synthesis, structure, and ethylene polymerization catalysis.

Published in:

Canadian Journal of Chemistry, 2006, v. 84, n. 5, p. 1, doi. 10.1139/V06-071

By:

Beddie, Chad;
Pingrong Wei;
Stephan, Douglas W.

Publication type:

Article

Transition metal complexes of a sterically demanding diimine ligand.

Published in:

Canadian Journal of Chemistry, 2005, v. 83, n. 5, p. 477, doi. 10.1139/V05-057

By:

Masuda, Jason D.;
Stephan, Douglas W.

Publication type:

Article

Homoleptic magnesium bis-phosphinimide derivatives.

Published in:

Canadian Journal of Chemistry, 2005, v. 83, n. 5, p. 430, doi. 10.1139/V05-059

By:

Hollink, Emily;
Wei, Pingrong;
Stephan, Douglas W.

Publication type:

Article

Synthesis and structure of a (NacNac)rhodium terminal dinitrogen complex.

Published in:

Canadian Journal of Chemistry, 2005, v. 83, n. 4, p. 324, doi. 10.1139/V05-012

By:

Masuda, Jason D.;
Stephan, Douglas W.

Publication type:

Article

Group IV phosphinimide amide complexes.

Published in:

Canadian Journal of Chemistry, 2004, v. 82, n. 11, p. 1634, doi. 10.1139/V04-141

By:

Hollink, Emily;
Wei, Pingrong;
Stephan, Douglas W.

Publication type:

Article

Altering molecular weight distributions: Benzyl–phosphinimide titanium complexes as ethylene polymerization catalysts.

Published in:

Canadian Journal of Chemistry, 2004, v. 82, n. 8, p. 1304, doi. 10.1139/V04-062

By:

Hollink, Emily;
Wei, Pingrong;
Stephan, Douglas W.

Publication type:

Article

The syntheses and structures of lithium phosphinimide and phosphinimine complexes.

Published in:

Canadian Journal of Chemistry, 2003, v. 81, n. 12, p. 1471, doi. 10.1139/v03-162

By:

Courtenay, Silke;
Wei, Pingrong;
Stephan, Douglas W.

Publication type:

Article

Synthesis and characterization of titanium complexes containing phosphinimido and tropidinyl ligands: Crystal structure of (trop)(t-Bu[sub 3] PN)TiCl[sub 2].

Published in:

Canadian Journal of Chemistry, 2002, v. 80, n. 11, p. 1618, doi. 10.1139/v02-170

By:

Brown, Steve J;
Gao, Xiaoliang;
Kowalchuk, Matthew G;
Spence, Rupert E.v.H.;
Stephan, Douglas W;
Swabey, John

Publication type:

Article

2001 Alcan Award LectureFrom academic research to industrial applications and back again.

Published in:

Canadian Journal of Chemistry, 2002, v. 80, n. 2, p. 125, doi. 10.1139/v01-203

By:

Stephan, Douglas W

Publication type:

Article

Cover Feature: Fluorination/Dearomatization of C6F5 Groups: An FLP Route to an Electrophilic Borane and Non‐Coordinating Anions (Chem. Eur. J. 43/2024).

Published in:

Chemistry - A European Journal, 2024, v. 30, n. 43, p. 1, doi. 10.1002/chem.202401776

By:

Kim, Hyehwang;
Mandal, Dipendu;
Ng, Joshua Kye Jin;
Qu, Zheng‐Wang;
Grimme, Stefan;
Stephan, Douglas W.

Publication type:

Article

Fluorination/Dearomatization of C6F5 Groups: An FLP Route to an Electrophilic Borane and Non‐Coordinating Anions.

Published in:

Chemistry - A European Journal, 2024, v. 30, n. 43, p. 1, doi. 10.1002/chem.202401776

By:

Kim, Hyehwang;
Mandal, Dipendu;
Ng, Joshua Kye Jin;
Qu, Zheng‐Wang;
Grimme, Stefan;
Stephan, Douglas W.

Publication type:

Article

Alkoxyphosphorane/Borane Cooperative Alkylations: A Frustrated Lewis Pair Version of the Mitsunobu Reaction.

Published in:

Chemistry - A European Journal, 2023, v. 29, n. 23, p. 1, doi. 10.1002/chem.202300264

By:

Chen, Ting;
Mei, Yanbo;
Liu, Liu Leo;
Zhao, Yufen;
Wu, Yile;
Stephan, Douglas W.

Publication type:

Article

Reactions of Diethylazo‐Dicarboxylate with Frustrated Lewis Pairs.

Published in:

Chemistry - A European Journal, 2022, v. 28, n. 53, p. 1, doi. 10.1002/chem.202201701

By:

Mandal, Dipendu;
Chen, Ting;
Qu, Zheng‐Wang;
Grimme, Stefan;
Stephan, Douglas W.

Publication type:

Article

The Non‐Ancillary Nature of Trimethylsilylamide Substituents in Boranes and Borinium Cations.

Published in:

Chemistry - A European Journal, 2022, v. 28, n. 27, p. 1, doi. 10.1002/chem.202200698

By:

Major, Christopher J.;
Qu, Zheng‐Wang;
Grimme, Stefan;
Stephan, Douglas W.

Publication type:

Article

The Varied Frustrated Lewis Pair Reactivity of the Germylene Phosphaketene (CH{(CMe)(2,6‐iPr2C6H3N)}2)GePCO.

Published in:

Chemistry - A European Journal, 2022, v. 28, n. 25, p. 1, doi. 10.1002/chem.202200666

By:

Wu, Yile;
Zhao, Zhao;
Chen, Ting;
Tan, Jingjie;
Qu, Zheng‐Wang;
Grimme, Stefan;
Zhao, Yufen;
Stephan, Douglas W.

Publication type:

Article

Bipyridinium and Phenanthrolinium Dications for Metal‐Free Hydrodefluorination: Distinctive Carbon‐Based Reactivity.

Published in:

Chemistry - A European Journal, 2021, v. 27, n. 45, p. 11730, doi. 10.1002/chem.202101534

By:

Burton, Katherine I.;
Elser, Iris;
Waked, Alexander E.;
Wagener, Tobias;
Andrews, Ryan J.;
Glorius, Frank;
Stephan, Douglas W.

Publication type:

Article

The Reactivity of Isomeric Nitrenium Lewis Acids with Phosphines, Carbenes, and Phosphide.

Published in:

Chemistry - A European Journal, 2021, v. 27, n. 8, p. 2861, doi. 10.1002/chem.202004798

By:

Zhu, Diya;
Qu, Zheng‐Wang;
Zhou, Jiliang;
Stephan, Douglas W.

Publication type:

Article

Phosphino‐Phosphination Reactions: Frustrated Lewis Pair Reactivity of Phosphino‐Phosphonium Cations with Alkynes.

Published in:

Angewandte Chemie, 2023, v. 135, n. 43, p. 1, doi. 10.1002/ange.202312587

By:

Kim, Hyehwang;
Qu, Zheng‐wang;
Grimme, Stefan;
Al‐Zuhaika, Nahil;
Stephan, Douglas W.

Publication type:

Article

Reactions of Frustrated Lewis Pairs with Chloro‐Diazirines: Cleavage of N=N Double Bonds.

Published in:

Angewandte Chemie, 2022, v. 134, n. 37, p. 1, doi. 10.1002/ange.202209241

By:

Mandal, Dipendu;
Chen, Ting;
Qu, Zheng‐Wang;
Grimme, Stefan;
Stephan, Douglas W.

Publication type:

Article

Berichtigung: Reactions of a Dilithiomethane with CO and N2O: An Avenue to an Anionic Ketene and a Hexafunctionalized Benzene.

Published in:

Angewandte Chemie, 2022, v. 134, n. 2, p. 1, doi. 10.1002/ange.202115217

By:

Xu, Maotong;
Wang, Tongtong;
Qu, Zheng‐Wang;
Grimme, Stefan;
Stephan, Douglas W.

Publication type:

Article

Selective Catalytic Frustrated Lewis Pair Hydrogenation of CO2 in the Presence of Silylhalides.

Published in:

Angewandte Chemie, 2021, v. 133, n. 49, p. 25975, doi. 10.1002/ange.202112233

By:

Wang, Tongtong;
Xu, Maotong;
Jupp, Andrew R.;
Qu, Zheng‐Wang;
Grimme, Stefan;
Stephan, Douglas W.

Publication type:

Article

Reactions of a Dilithiomethane with CO and N2O: An Avenue to an Anionic Ketene and a Hexafunctionalized Benzene.

Published in:

Angewandte Chemie, 2021, v. 133, n. 48, p. 25485, doi. 10.1002/ange.202111486

By:

Xu, Maotong;
Wang, Tongtong;
Qu, Zheng‐Wang;
Grimme, Stefan;
Stephan, Douglas W.

Publication type:

Article

A Primary Acyl Phosphine Stabilized by a Phosphonium Ylide.

Published in:

Angewandte Chemie, 2021, v. 133, n. 34, p. 18695, doi. 10.1002/ange.202106846

By:

Petrone, David A.;
Szkop, Kevin M.;
Miao, Linkun;
St. Onge, Piers;
Qu, Zheng‐Wang;
Grimme, Stefan;
Stephan, Douglas W.

Publication type:

Article

Facile Synthesis of Cyanide and Isocyanides from CO.

Published in:

Angewandte Chemie, 2021, v. 133, n. 31, p. 17102, doi. 10.1002/ange.202105909

By:

Xu, Maotong;
Kooij, Bastiaan;
Wang, Tongtong;
Lin, Jack H.;
Qu, Zheng‐Wang;
Grimme, Stefan;
Stephan, Douglas W.

Publication type:

Article

Reactions of B2(o‐tolyl)4 with Boranes: Assembly of the Pentaborane(9), HB[B(o‐tolyl)(μ‐H)]4.

Published in:

Angewandte Chemie, 2021, v. 133, n. 15, p. 8613, doi. 10.1002/ange.202101054

By:

Bamford, Karlee L.;
Qu, Zheng‐Wang;
Stephan, Douglas W.

Publication type:

Article

Single Electron Transfer to Diazomethane–Borane Adducts Prompts C−H Bond Activations.

Published in:

Angewandte Chemie, 2019, v. 131, n. 51, p. 18658, doi. 10.1002/ange.201912338

By:

Cao, Levy L.;
Zhou, Jiliang;
Qu, Zheng‐Wang;
Stephan, Douglas W.

Publication type:

Article

Base‐Stabilized [PO]+/[PO2]+ Cations.

Published in:

Angewandte Chemie, 2019, v. 131, n. 50, p. 18444, doi. 10.1002/ange.201912009

By:

Zhou, Jiliang;
Liu, Liu Leo;
Cao, Levy L.;
Stephan, Douglas W.

Publication type:

Article

Synthesis of Urea Derivatives from CO2 and Silylamines.

Published in:

Angewandte Chemie, 2019, v. 131, n. 17, p. 5763, doi. 10.1002/ange.201900058

By:

Xu, Maotong;
Jupp, Andrew R.;
Ong, Maegan S. E.;
Burton, Katherine I.;
Chitnis, Saurabh S.;
Stephan, Douglas W.

Publication type:

Article

The Arene‐Stabilized η5‐Pentamethylcyclopentadienyl Arsenic Dication [(η5‐Cp*)As(toluene)]2+.

Published in:

Angewandte Chemie, 2019, v. 131, n. 16, p. 5461, doi. 10.1002/ange.201902039

By:

Zhou, Jiliang;
Liu, Liu Leo;
Cao, Levy L.;
Stephan, Douglas W.

Publication type:

Article

Acyl‐Phosphide Anions via an Intermediate with Carbene Character: Reactions of K[PtBu2] and CO.

Published in:

Angewandte Chemie, 2019, v. 131, n. 11, p. 3586, doi. 10.1002/ange.201814562

By:

Xu, Maotong;
Jupp, Andrew R.;
Stephan, Douglas W.

Publication type:

Article

Facile Cleavage of the P=P Double Bond in Vinyl‐Substituted Diphosphenes.

Published in:

Angewandte Chemie, 2019, v. 131, n. 1, p. 279, doi. 10.1002/ange.201812592

By:

Liu, Liu Leo;
Cao, Levy L.;
Zhou, Jiliang;
Stephan, Douglas W.

Publication type:

Article

Reduktion von Phosphanoxiden mit Oxalylchlorid und Wasserstoff, vermittelt durch ein elektrophiles Phosphoniumkation.

Published in:

Angewandte Chemie, 2018, v. 130, n. 46, p. 15473, doi. 10.1002/ange.201809275

By:

Stepen, Arne J.;
Bursch, Markus;
Grimme, Stefan;
Stephan, Douglas W.;
Paradies, Jan

Publication type:

Article

Nitrogen‐Based Lewis Acids Derived from Phosphonium Diazo Cations.

Published in:

Angewandte Chemie, 2018, v. 130, n. 37, p. 12110, doi. 10.1002/ange.201804183

By:

Waked, Alexander E.;
Ostadsharif Memar, Rouzbeh;
Stephan, Douglas W.

Publication type:

Article

Alkali Metal Species in the Reversible Activation of H2.

Published in:

Angewandte Chemie, 2018, v. 130, n. 34, p. 11216, doi. 10.1002/ange.201806849

By:

Xu, Maotong;
Jupp, Andrew R.;
Qu, Zheng‐Wang;
Stephan, Douglas W.

Publication type:

Article

Catalytic Reduction of CO2 to CO by Using Zinc(II) and In Situ Generated Carbodiphosphoranes.

Published in:

Angewandte Chemie International Edition, 2013, v. 52, n. 9, p. 2516, doi. 10.1002/anie.201208817

By:

Dobrovetsky, Roman;
Stephan, Douglas W.

Publication type:

Article

Heterolytic Activation of H2 Using a Mechanically Interlocked Molecule as a Frustrated Lewis Base.

Published in:

Angewandte Chemie International Edition, 2013, v. 52, n. 3, p. 960, doi. 10.1002/anie.201207783

By:

Caputo, Christopher B.;
Zhu, Kelong;
Vukotic, V. Nicholas;
Loeb, Stephen J.;
Stephan, Douglas W.

Publication type:

Article

Cover Picture: Heterolytic Activation of H2 Using a Mechanically Interlocked Molecule as a Frustrated Lewis Base (Angew. Chem. Int. Ed. 3/2013).

Published in:

Angewandte Chemie International Edition, 2013, v. 52, n. 3, p. 773, doi. 10.1002/anie.201209490

By:

Caputo, Christopher B.;
Zhu, Kelong;
Vukotic, V. Nicholas;
Loeb, Stephen J.;
Stephan, Douglas W.

Publication type:

Article

Frustrated Lewis Pair Inspired Carbon Dioxide Reduction by a Ruthenium Tris(aminophosphine) Complex.

Published in:

Angewandte Chemie International Edition, 2012, v. 51, n. 45, p. 11343, doi. 10.1002/anie.201205741

By:

Sgro, Michael J.;
Stephan, Douglas W.

Publication type:

Article