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Direct Deprotonative Functionalization of α,α‐Difluoromethyl Ketones using a Catalytic Organosuperbase.
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- Angewandte Chemie, 2023, v. 135, n. 10, p. 1, doi. 10.1002/ange.202215899
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- Article
Direct Deprotonative Functionalization of α,α‐Difluoromethyl Ketones using a Catalytic Organosuperbase.
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- Angewandte Chemie International Edition, 2023, v. 62, n. 10, p. 1, doi. 10.1002/anie.202215899
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- Article
A historical analysis of the policy on intractable diseases in Japan and its peculiarity.
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- Dynamis, 2022, v. 42, n. 2, p. 397, doi. 10.30827/dynamis.v42i2.27715
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- Article
Mono‐Gold(I)‐Catalyzed Enantioselective Intermolecular Reaction of Ynones with Styrenes: Tandem Diels–Alder and Ene Sequence.
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- Helvetica Chimica Acta, 2021, v. 104, n. 2, p. 1, doi. 10.1002/hlca.202000198
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- Article
Facile C−F Bond Activation Approach to FAMT‐Based Difluoromethyl‐BNCT Drug Candidates.
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- Helvetica Chimica Acta, 2021, v. 104, n. 2, p. 1, doi. 10.1002/hlca.202000211
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- Article
Orphans in the Market: The History of Orphan Drug Policy.
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- Social History of Medicine, 2019, v. 32, n. 3, p. 609, doi. 10.1093/shm/hkx098
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- Article
Palladium‐Catalyzed Negishi Cross‐Coupling Reaction of Difluoroiodomethane with Arylzinc Reagents.
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- Asian Journal of Organic Chemistry, 2019, v. 8, n. 5, p. 698, doi. 10.1002/ajoc.201900106
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- Article
Asymmetric “Acetylenic” [3+2] Cycloaddition of Nitrones Catalyzed by Cationic Chiral Pd<sup>II</sup> Lewis Acid.
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- Chemistry - An Asian Journal, 2018, v. 13, n. 19, p. 2838, doi. 10.1002/asia.201801016
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- Article
Cationic Chiral Pd‐Catalyzed “Acetylenic” Diels–Alder Reaction: Computational Analysis of Reversal in Enantioselectivity.
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- Chemistry - An Asian Journal, 2018, v. 13, n. 19, p. 2842, doi. 10.1002/asia.201801035
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- Article
Observation of a Metastable P‐Heterocyclic Radical by Muonium Addition to a 1,3‐Diphosphacyclobutane‐2,4‐diyl.
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- Angewandte Chemie, 2018, v. 130, n. 28, p. 8744, doi. 10.1002/ange.201804306
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- Article
Observation of a Metastable P‐Heterocyclic Radical by Muonium Addition to a 1,3‐Diphosphacyclobutane‐2,4‐diyl.
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- Angewandte Chemie International Edition, 2018, v. 57, n. 28, p. 8608, doi. 10.1002/anie.201804306
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- Article
CF<sub>3</sub>‐Inspired Synthesis of Air‐Tolerant 9‐Phosphaanthracenes that Feature Fluorescence and Crystalline Polymorphs.
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- Chemistry - An Asian Journal, 2018, v. 13, n. 7, p. 830, doi. 10.1002/asia.201701669
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- Article
Air-Tolerant 1-Amino-1,3-diphosphacyclobutane-2,4-diyls Featuring Strong Electron-Donating Properties and Small HOMO-LUMO Gaps.
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- European Journal of Inorganic Chemistry, 2017, v. 2017, n. 24, p. 3048, doi. 10.1002/ejic.201700432
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- Article
2,3-Dihydro-1H-naphtho[1,8-cd]borinine as a Potent Precursor for Open-Shell Singlet B-Heterocycles.
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- European Journal of Inorganic Chemistry, 2017, v. 2017, n. 22, p. 2936, doi. 10.1002/ejic.201700372
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- Article
Cyclic-Protected Hexafluoroacetone as an Air-Stable Liquid Reagent for Trifluoromethylations.
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- European Journal of Organic Chemistry, 2016, v. 2016, n. 23, p. 4099, doi. 10.1002/ejoc.201600711
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- Article
Rhodium-Catalyzed Hydrocarboxylation of Olefins with Carbon Dioxide.
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- European Journal of Organic Chemistry, 2016, v. 2016, n. 19, p. 3166, doi. 10.1002/ejoc.201600338
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- Article
Access to Air-Stable 1,3-Diphosphacyclobutane-2,4-diyls by an Arylation Reaction with Arynes.
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- Angewandte Chemie, 2016, v. 128, n. 26, p. 7651, doi. 10.1002/ange.201601907
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- Article
Access to Air-Stable 1,3-Diphosphacyclobutane-2,4-diyls by an Arylation Reaction with Arynes.
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- Angewandte Chemie International Edition, 2016, v. 55, n. 26, p. 7525, doi. 10.1002/anie.201601907
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- Article
Computational S<sub>N</sub>2-Type Mechanism for the Difluoromethylation of Lithium Enolate with Fluoroform through Bimetallic C−F Bond Dual Activation.
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- Chemistry - A European Journal, 2016, v. 22, n. 26, p. 8796, doi. 10.1002/chem.201601090
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- Article
Dynamic Chirality Control of tropos DPCB-digold Skeleton by Chiral Binaphthyldicarboxylate.
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- Chemistry - An Asian Journal, 2016, v. 11, n. 6, p. 823, doi. 10.1002/asia.201501326
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- Article
Lewis Acid Catalyzed Asymmetric Three-Component Coupling Reaction: Facile Synthesis of α-Fluoromethylated Tertiary Alcohols.
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- Chemistry - A European Journal, 2015, v. 21, n. 49, p. 17565, doi. 10.1002/chem.201503631
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- Article
Stable but Reactive Perfluoroalkylzinc Reagents: Application in Ligand-Free Copper-Catalyzed Perfluoroalkylation of Aryl Iodides.
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- Chemistry - A European Journal, 2015, v. 21, n. 1, p. 96, doi. 10.1002/chem.201405677
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- Article
Preparation via Sterically Promoted S<sub>N</sub>2′ Substitution and Structural Characteristics of a Mes*-Substituted Tertiary Ethynylphosphine.
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- Heteroatom Chemistry, 2014, v. 25, n. 5, p. 422, doi. 10.1002/hc.21182
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- Article
π-Extended DPCB for Activation-Free Homogeneous Gold Catalysis.
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- ChemCatChem, 2014, v. 6, n. 8, p. 2292, doi. 10.1002/cctc.201402158
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- Article
Direct α-Siladifluoromethylation of Lithium Enolates with Ruppert-Prakash Reagent via CF Bond Activation.
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- Chemistry - A European Journal, 2014, v. 20, n. 10, p. 2750, doi. 10.1002/chem.201304473
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- Article
Paradigm Shift from Alkaline (Earth) Metals to Early Transition Metals in Fluoroorganometal Chemistry: Perfluoroalkyl Titanocene(III) Reagents Prepared via Not Titanocene(II) but Titanocene(III) Species.
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- Chemistry - A European Journal, 2014, v. 20, n. 8, p. 2382, doi. 10.1002/chem.201303089
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- Article
Direct Synthesis of a Trifluoromethyl Copper Reagent from Trifluoromethyl Ketones: Application to Trifluoromethylation.
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- Chemistry - A European Journal, 2013, v. 19, n. 52, p. 17692, doi. 10.1002/chem.201303828
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- Article
Silyl Effects on 1,3-Diphosphacyclobutane-2,4-diyl: Ring-Opening of Tetrahydrofuran and Promotion of Reductive PC Cleavage.
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- Chemistry - An Asian Journal, 2013, v. 8, n. 9, p. 1976, doi. 10.1002/asia.201300564
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- Article
Direct Preparation of Trifluoromethylindium Reagents from Trifluoromethyl Iodide: Effective Trifluoromethylation and Perfluoroalkylation Reagents.
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- European Journal of Organic Chemistry, 2012, v. 2012, n. 36, p. 7043, doi. 10.1002/ejoc.201201116
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- Article
Umpolung of Fluoroform by CF Bond Activation: Direct Difluoromethylation of Lithium Enolates.
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- Angewandte Chemie, 2012, v. 124, n. 38, p. 9673, doi. 10.1002/ange.201203588
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- Article
Umpolung of Fluoroform by CF Bond Activation: Direct Difluoromethylation of Lithium Enolates.
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- Angewandte Chemie International Edition, 2012, v. 51, n. 38, p. 9535, doi. 10.1002/anie.201203588
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- Article
Enantioselective Intermolecular Carbon-Carbon Bond Formation of Glyoxylate Imines with Allylstannanes Catalyzed by tropos BIPHEP-Gold(I) Complexes with Au-Au Interactions.
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- Chemistry - A European Journal, 2011, v. 17, n. 50, p. 13950, doi. 10.1002/chem.201103023
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- Article
Combination of sp<sup>2</sup>- and sp<sup>3</sup>-Type Phosphorus Atoms for Gold Chemistry: Preparation, Structure, and Catalytic Activity of Gold Complexes That Bear Ligated 2-Silyl-1,3-diphosphapropenes.
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- Chemistry - An Asian Journal, 2011, v. 6, n. 11, p. 3077, doi. 10.1002/asia.201100310
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- Article
Corrigendum: Synergistic Effect: Hydroalkoxylation of Allenes through Combination of Enantiopure BIPHEP-Gold Complexes and Chiral Anions.
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- Advanced Synthesis & Catalysis, 2011, v. 353, n. 16, p. 2882, doi. 10.1002/adsc.201100838
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- Article
Palladium-Catalyzed Enantioselective Ene and Aldol Reactions with Isatins, Keto Esters, and Diketones: Reliable Approach to Chiral Tertiary Alcohols.
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- European Journal of Organic Chemistry, 2011, v. 2011, n. 1, p. 62, doi. 10.1002/ejoc.201001356
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- Article
Catalytic Enantioselective Arylation of Glyoxylate with Arylsilanes: Practical Synthesis of Optically Active Mandelic Acid Derivatives.
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- Chemistry - An Asian Journal, 2010, v. 5, n. 11, p. 2346, doi. 10.1002/asia.201000522
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- Article
Activation of CF Bonds in Preference to CI Bonds: Difluoromethylation of Lithium Enolates with Trifluoromethyl Iodide.
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- Angewandte Chemie, 2010, v. 122, n. 22, p. 3907, doi. 10.1002/ange.201000435
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- Article
Activation of CF Bonds in Preference to CI Bonds: Difluoromethylation of Lithium Enolates with Trifluoromethyl Iodide.
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- Angewandte Chemie International Edition, 2010, v. 49, n. 22, p. 3819, doi. 10.1002/anie.201000435
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- Article
Asymmetric catalysis of homo-coupling of 3-substituted naphthylamine and hetero-coupling with 3-substituted naphthol leading to 3,3′-dimethyl-2,2′-diaminobinaphthyl and -2-amino-2′-hydroxybinaphthyl.
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- Chirality, 2010, v. 22, n. 2, p. 224, doi. 10.1002/chir.20731
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- Article
Axial Chirality Control of Gold(biphep) Complexes by Chiral Anions: Application to Asymmetric Catalysis.
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- Angewandte Chemie International Edition, 2009, v. 48, n. 33, p. 6073, doi. 10.1002/anie.200902084
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- Article
Fluorous 'racemic' mixture synthesis: Polysaccharide-based chiral columns for simultaneous demix and enantioseparation of racemic fluorous tagged compounds.
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- Chirality, 2008, v. 20, n. 3/4, p. 597, doi. 10.1002/chir.20487
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- Article
Asymmetric Synthesis of Antithrombotic Agent M55529: The First Enantioselective Cyclic N,O-Acetal Formation.
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- European Journal of Organic Chemistry, 2006, v. 2006, n. 10, p. 2269, doi. 10.1002/ejoc.200600124
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- Article
Metal enolates of α-CF<sub>3</sub> ketones: theoretical guideline, direct generation, and synthetic use.
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- Chemical Record, 2006, v. 6, n. 1, p. 1, doi. 10.1002/tcr.20066
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- Article
Enantiodiscrimination and Enantiocontrol of Neutral and Cationic PtII Complexes Bearing the Tropos Biphep Ligand: Application to Asymmetric Lewis Acid CatalysisBiphep is 2,2′-bis(diphenylphosphanyl)biphenyl.
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- Angewandte Chemie, 2005, v. 117, n. 44, p. 7423, doi. 10.1002/ange.200502682
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- Article
Enantiodiscrimination and Enantiocontrol of Neutral and Cationic PtII Complexes Bearing the Tropos Biphep Ligand: Application to Asymmetric Lewis Acid CatalysisBiphep is 2,2′-bis(diphenylphosphanyl)biphenyl.
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- Angewandte Chemie International Edition, 2005, v. 44, n. 44, p. 7257, doi. 10.1002/anie.200502682
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- Article
Enantioselective Heck-Type Reaction Catalyzed by tropos-Pd(II) Complex with Chiraphos Ligand.
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- Advanced Synthesis & Catalysis, 2005, v. 347, n. 11-13, p. 1569, doi. 10.1002/adsc.200505154
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- Article
Chiral aminonaphthol-catalyzed enantioselective carbonyl addition of diethylzinc to aromatic aldehydes high-throughput screened by CD-HPLC analysis.
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- Chirality, 2005, v. 17, n. 8, p. 476, doi. 10.1002/chir.20183
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- Article
Atropos but Achiral Tris(phosphanyl)biphenyl Ligands for Ru-Catalyzed Asymmetric Hydrogenation ( K. Aikawa is grateful to the Japan Society for the Promotion of Science for Young Scientists for a research fellowship. ).
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- Angewandte Chemie, 2003, v. 115, n. 44, p. 5613, doi. 10.1002/ange.200352277
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- Article
Helical Chirality Control of Palladium Complexes That Bear a Tetrakis(phosphanyl)terphenyl Ligand: Application as Asymmetric Lewis Acid Catalysts ( We are grateful to Dr. Kenji Yoza and Mr. Kazuyoshi Kitajima in the Nippon Bruker Co. for X-ray crystallographic analysis. K. Aikawa is grateful to the Japan Society for the Promotion of Science for Young Scientists for a research fellowship. )
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- Angewandte Chemie, 2003, v. 115, n. 44, p. 5616, doi. 10.1002/ange.200352300
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- Article
Atropos but Achiral Tris(phosphanyl)biphenyl Ligands for Ru-Catalyzed Asymmetric Hydrogenation ( K. Aikawa is grateful to the Japan Society for the Promotion of Science for Young Scientists for a research fellowship. ).
- Published in:
- Angewandte Chemie International Edition, 2003, v. 42, n. 44, p. 5455, doi. 10.1002/anie.200352277
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- Article