Works by Gómez‐Bengoa, Enrique

Results: 40

Highly Efficient Asymmetric Michael Addition of Aldehydes to Nitroalkenes Catalyzed by a Simple trans-4-HydroxyprolylamideThis work was financially supported by The University of the Basque Country (UPV/EHU) and the Ministerio de Educación y Ciencia (MEC, Spain). A predoctoral grant to S.V. from MEC is also acknowledged. We also thank M. Alcalá and A. Lizarraga for their help with some experimental work and the SGI/IZO-SGIker UPV/EHU for allocation of computational resources.

Published in:

Angewandte Chemie, 2006, v. 118, n. 36, p. 6130, doi. 10.1002/ange.200602207

By:

Claudio Palomo;
Silvia Vera;
Antonia Mielgo;
Enrique Gómez-Bengoa

Publication type:

Article

Olefin Epoxidation Catalyzed by cis-Dioxdomolybdenum(VI) Complexes Containing Chiral Alkoxo-Imino Ligands Derived from (+)-α-Pinene.

Published in:

European Journal of Inorganic Chemistry, 2012, v. 2012, n. 17, p. 2940, doi. 10.1002/ejic.201200144

By:

Chahboun, Ghaita;
Brito, Jose Angel;
Royo, Beatriz;
El Amrani, Mohamed Amin;
Gómez-Bengoa, Enrique;
Mosquera, Marta E. G.;
Cuenca, Tomás;
Royo, Eva

Publication type:

Article

Four‐Step Synthesis of (−)‐4‐epi‐Presilphiperfolan‐8α‐ol by Intramolecular Iron Hydride Atom Transfer‐Mediated Ketone‐Alkene Coupling and Studies to Access trans‐Hydrindanols with a Botryane Scaffold

Published in:

Chemistry - A European Journal, 2023, v. 29, n. 15, p. 1, doi. 10.1002/chem.202203286

By:

Saladrigas, Mar;
Gómez‐Bengoa, Enrique;
Bonjoch, Josep;
Bradshaw, Ben

Publication type:

Article

An Expedient Method for the Umpolung Coupling of Enols with Heteronucleophiles**.

Published in:

Chemistry - A European Journal, 2022, v. 28, n. 44, p. 1, doi. 10.1002/chem.202201000

By:

García‐Vázquez, Víctor;
Carretero Cerdán, Alba;
Sanz‐Marco, Amparo;
Gómez‐Bengoa, Enrique;
Martín‐Matute, Belén

Publication type:

Article

Synthesis of Cyclometalated Gold(III) Complexes via Catalytic Rhodium to Gold(III) Transmetalation.

Published in:

Angewandte Chemie, 2022, v. 134, n. 20, p. 1, doi. 10.1002/ange.202116755

By:

Martín, Jaime;
Gómez‐Bengoa, Enrique;
Genoux, Alexandre;
Nevado, Cristina

Publication type:

Article

Brønsted Base Catalyzed One‐Pot Synthesis of Stereodefined Six‐Member Carbocycles Featuring Transient Trienolates and a Key Intramolecular 1,6‐Addition.

Published in:

Angewandte Chemie, 2019, v. 131, n. 40, p. 14388, doi. 10.1002/ange.201908693

By:

Olaizola, Olatz;
Iriarte, Igor;
Zanella, Giovanna;
Gómez‐Bengoa, Enrique;
Ganboa, Iñaki;
Oiarbide, Mikel;
Palomo, Claudio

Publication type:

Article

Domino Reactions with Dicyanoalkenes and Fluorinated Conjugated Sulfinyl Imines. A Convenient Strategy for the Generation of Structural Diversity.

Published in:

Advanced Synthesis & Catalysis, 2024, v. 366, n. 4, p. 970, doi. 10.1002/adsc.202301123

By:

Gaviña, Daniel;
Escolano, Marcos;
Sotorríos, Lía;
Gómez‐Bengoa, Enrique;
López‐Ortiz, Fernando;
Sánchez‐Roselló, María;
del Pozo, Carlos

Publication type:

Article

Manganese‐Catalyzed Multicomponent Synthesis of Tetrasubstituted Propargylamines: System Development and Theoretical Study.

Published in:

Advanced Synthesis & Catalysis, 2020, v. 362, n. 18, p. 3872, doi. 10.1002/adsc.202000566

By:

Neofotistos, Stavros P.;
Tzouras, Nikolaos V.;
Pauze, Martin;
Gómez‐Bengoa, Enrique;
Vougioukalakis, Georgios C.

Publication type:

Article

N-(Diazoacetyl)oxazolidin-2-thiones as Sulfur-Donor Reagents: Asymmetric Synthesis of Thiiranes from Aldehydes.

Published in:

Angewandte Chemie International Edition, 2012, v. 51, n. 43, p. 10856, doi. 10.1002/anie.201204771

By:

Cano, Israel;
Gómez-Bengoa, Enrique;
Landa, Aitor;
Maestro, Miguel;
Mielgo, Antonia;
Olaizola, Iurre;
Oiarbide, Mikel;
Palomo, Claudio

Publication type:

Article

Regio- and Enantioselective Direct Oxyamination Reaction of Aldehydes Catalyzed by α,α-Diphenylprolinol Trimethylsilyl Ether.

Published in:

Angewandte Chemie International Edition, 2007, v. 46, n. 42, p. 8054, doi. 10.1002/anie.200703001

By:

Palomo, Claudio;
Vera, Silvia;
Velilla, Irene;
Mielgo, Antonia;
Gómez-Bengoa, Enrique

Publication type:

Article

Synthesis of 3‐Amino‐1‐benzothiophene‐1,1‐diones by Alkyne Directed Hydroarylation and 1/N→3/C‐Sulfonyl Migration.

Published in:

European Journal of Organic Chemistry, 2018, v. 2018, n. 39, p. 5435, doi. 10.1002/ejoc.201801062

By:

Bernar, Ivan;
Blanco‐Ania, Daniel;
Stok, Sophie J.;
Sotorríos, Lia;
Gómez‐Bengoa, Enrique;
Rutjes, Floris P. J. T.

Publication type:

Article

Annulated N-Heterocycles by Tandem Gold(I)-Catalyzed [3,3]-Rearrangement/Nazarov Reaction of Propargylic Ester Derivatives: an Experimental and Computational Study.

Published in:

European Journal of Organic Chemistry, 2015, v. 2015, n. 18, p. 3943, doi. 10.1002/ejoc.201500462

By:

Petrović, Martina;
Scarpi, Dina;
Fiser, Béla;
Gómez‐Bengoa, Enrique;
Occhiato, Ernesto G.

Publication type:

Article

Gold-Catalysed Synthesis of Exocyclic Vinylogous Amides and β-Amino Ketones: A Detailed Study on the 5-exo/6-endo-dig Selectivity, Methodology and Scope.

Published in:

European Journal of Organic Chemistry, 2015, p. 3251, doi. 10.1002/ejoc.201500205

By:

Scarpi, Dina;
Begliomini, Stefano;
Prandi, Cristina;
Oppedisano, Alberto;
Deagostino, Annamaria;
Gómez-Bengoa, Enrique;
Fiser, Béla;
Occhiato, Ernesto G.

Publication type:

Article

Gold-Catalysed Synthesis of Exocyclic Vinylogous Amides and β-Amino Ketones: A Detailed Study on the 5- exo/6- endo- dig Selectivity, Methodology and Scope.

Published in:

European Journal of Organic Chemistry, 2015, v. 2015, n. 15, p. 3251, doi. 10.1002/ejoc.201500205

By:

Scarpi, Dina;
Begliomini, Stefano;
Prandi, Cristina;
Oppedisano, Alberto;
Deagostino, Annamaria;
Gómez-Bengoa, Enrique;
Fiser, Béla;
Occhiato, Ernesto G.

Publication type:

Article

Pyrimidine-Derived Prolinamides as Recoverable Bifunctional Organocatalysts for Enantioselective Inter- and Intramolecular Aldol Reactions under Solvent-Free Conditions.

Published in:

European Journal of Organic Chemistry, 2015, v. 2015, n. 12, p. 2614, doi. 10.1002/ejoc.201500007

By:

Vizcaíno‐Milla, Pascuala;
Sansano, José M.;
Nájera, Carmen;
Fiser, Béla;
Gómez‐Bengoa, Enrique

Publication type:

Article

Solvent-Induced Reversal of Enantioselectivity in the Synthesis of Succinimides by the Addition of Aldehydes to Maleimides Catalysed by Carbamate-Monoprotected 1,2-Diamines.

Published in:

European Journal of Organic Chemistry, 2015, v. 2015, n. 6, p. 1218, doi. 10.1002/ejoc.201403415

By:

Flores‐Ferrándiz, Jesús;
Fiser, Béla;
Gómez‐Bengoa, Enrique;
Chinchilla, Rafael

Publication type:

Article

Enantioselective Synthesis of Succinimides by Michael Addition of Aldehydes to Maleimides Organocatalyzed by Chiral Primary Amine-Guanidines.

Published in:

European Journal of Organic Chemistry, 2013, v. 2013, n. 23, p. 5085, doi. 10.1002/ejoc.201300492

By:

Avila, Angel;
Chinchilla, Rafael;
Gómez‐Bengoa, Enrique;
Nájera, Carmen

Publication type:

Article

Enantioselective Synthesis of Succinimides by Michael Addition of 1,3-Dicarbonyl Compounds to Maleimides Catalyzed by a Chiral Bis(2-aminobenzimidazole) Organocatalyst.

Published in:

European Journal of Organic Chemistry, 2013, v. 2013, n. 8, p. 1434, doi. 10.1002/ejoc.201201046

By:

Gómez‐Torres, Eduardo;
Alonso, Diego A.;
Gómez‐Bengoa, Enrique;
Nájera, Carmen

Publication type:

Article

Synthesis of Cyclometalated Gold(III) Complexes via Catalytic Rhodium to Gold(III) Transmetalation.

Published in:

Angewandte Chemie International Edition, 2022, v. 61, n. 20, p. 1, doi. 10.1002/anie.202116755

By:

Martín, Jaime;
Gómez‐Bengoa, Enrique;
Genoux, Alexandre;
Nevado, Cristina

Publication type:

Article

Brønsted Base Catalyzed One‐Pot Synthesis of Stereodefined Six‐Member Carbocycles Featuring Transient Trienolates and a Key Intramolecular 1,6‐Addition.

Published in:

Angewandte Chemie International Edition, 2019, v. 58, n. 40, p. 14250, doi. 10.1002/anie.201908693

By:

Olaizola, Olatz;
Iriarte, Igor;
Zanella, Giovanna;
Gómez‐Bengoa, Enrique;
Ganboa, Iñaki;
Oiarbide, Mikel;
Palomo, Claudio

Publication type:

Article

α‐Branched Ketone Dienolates: Base‐Catalysed Generation and Regio‐ and Enantioselective Addition Reactions.

Published in:

Chemistry - A European Journal, 2019, v. 25, n. 41, p. 9701, doi. 10.1002/chem.201901694

By:

Urruzuno, Iñaki;
Mugica, Odei;
Zanella, Giovanna;
Vera, Silvia;
Gómez‐Bengoa, Enrique;
Oiarbide, Mikel;
Palomo, Claudio

Publication type:

Article

Synthetic and Mechanistic Investigation of an Oxime Ether Electrocyclization Approach to Heteroaromatic Boronic Acid Derivatives.

Published in:

Chemistry - A European Journal, 2018, v. 24, n. 38, p. 9530, doi. 10.1002/chem.201802350

By:

Mora‐Radó, Helena;
Sotorríos, Lia;
Ball‐Jones, Matthew P.;
Bialy, Laurent;
Czechtizky, Werngard;
Méndez, María;
Gómez‐Bengoa, Enrique;
Harrity, Joseph P. A.

Publication type:

Article

Expeditious diastereoselective synthesis of elaborated ketones via remote Csp3-H functionalization.

Published in:

Nature Communications, 2017, v. 8, n. 1, p. 13832, doi. 10.1038/ncomms13832

By:

Shu, Wei;
Lorente, Adriana;
Gómez-Bengoa, Enrique;
Nevado, Cristina

Publication type:

Article

Directed C−H Allylation of Aromatic Carboxamides with Allyl Aryl Ethers under Cp*Co(III)‐Catalysis.

Published in:

European Journal of Organic Chemistry, 2024, v. 27, n. 1, p. 1, doi. 10.1002/ejoc.202301090

By:

Carral‐Menoyo, Asier;
Barbolla, Iratxe;
Santiago, Carlos;
Espinel, Martín;
Sotomayor, Nuria;
Gómez‐Bengoa, Enrique;
Lete, Esther

Publication type:

Article

Highly Efficient Asymmetric Michael Addition of Aldehydes to Nitroalkenes Catalyzed by a Simple trans-4-HydroxyprolylamideThis work was financially supported by The University of the Basque Country (UPV/EHU) and the Ministerio de Educación y Ciencia (MEC, Spain). A predoctoral grant to S.V. from MEC is also acknowledged. We also thank M. Alcalá and A. Lizarraga for their help with some experimental work and the SGI/IZO-SGIker UPV/EHU for allocation of computational resources.

Published in:

Angewandte Chemie International Edition, 2006, v. 45, n. 36, p. 5984, doi. 10.1002/anie.200602207

By:

Claudio Palomo;
Silvia Vera;
Antonia Mielgo;
Enrique Gómez-Bengoa

Publication type:

Article

A Modular Class of Fluorescent Difluoroboranes: Synthesis, Structure, Optical Properties, Theoretical Calculations and Applications for Biological Imaging.

Published in:

Chemistry - A European Journal, 2016, v. 22, n. 35, p. 12430, doi. 10.1002/chem.201601915

By:

Bachollet, Sylvestre P. J. T.;
Volz, Daniel;
Fiser, Béla;
Münch, Stephan;
Rönicke, Franziska;
Carrillo, Jokin;
Adams, Harry;
Schepers, Ute;
Gómez‐Bengoa, Enrique;
Bräse, Stefan;
Harrity, Joseph P. A.

Publication type:

Article

Gold-Catalyzed 1,2-/1,2-Bis-acetoxy Migration of 1,4-Bis-propargyl Acetates: A Mechanistic Study.

Published in:

Chemistry - A European Journal, 2012, v. 18, n. 22, p. 6811, doi. 10.1002/chem.201103472

By:

de Haro, Teresa;
Gómez-Bengoa, Enrique;
Cribiú, Riccardo;
Huang, Xiaogen;
Nevado, Cristina

Publication type:

Article

The First Gold(III) Formate: Evidence for β-Hydride Elimination.

Published in:

Angewandte Chemie, 2017, v. 129, n. 42, p. 13042, doi. 10.1002/ange.201705557

By:

Kumar, Roopender;
Krieger, Jean‐Philippe;
Gómez‐Bengoa, Enrique;
Fox, Thomas;
Linden, Anthony;
Nevado, Cristina

Publication type:

Article

N-(Diazoacetyl)oxazolidin-2-thiones as Sulfur-Donor Reagents: Asymmetric Synthesis of Thiiranes from Aldehydes.

Published in:

Angewandte Chemie, 2012, v. 124, n. 43, p. 11014, doi. 10.1002/ange.201204771

By:

Cano, Israel;
Gómez-Bengoa, Enrique;
Landa, Aitor;
Maestro, Miguel;
Mielgo, Antonia;
Olaizola, Iurre;
Oiarbide, Mikel;
Palomo, Claudio

Publication type:

Article

Unravelling mechanistic insights in the platinum-catalysed dihydroalkoxylation of allenes.

Published in:

Pure & Applied Chemistry, 2020, v. 92, n. 1, p. 167, doi. 10.1515/pac-2019-0214

By:

Quirós, María Teresa;
Gómez-Bengoa, Enrique;
Muñoz, María Paz

Publication type:

Article

Cationic Intermediates in the Intramolecular Insertion of Alkenes into (η3-Allyl)palladium( II) Complexes.

Published in:

Angewandte Chemie International Edition, 1997, v. 36, n. 7, p. 767, doi. 10.1002/anie.199707671

By:

Gómez-Bengoa, Enrique;
Cuerva, Juan Manuel;
Echavarren, Antonio M.;
Martorell, Gabriel

Publication type:

Article

Brønsted Acid Assisted Regio- and Enantioselective Direct O-Nitroso Aldol Reaction Catalysed by α,α-Diphenylprolinol Trimethylsilyl Ether.

Published in:

Chemistry - A European Journal, 2010, v. 16, n. 25, p. 7496, doi. 10.1002/chem.201000376

By:

Mielgo, Antonia;
Velilla, Irene;
Gómez-Bengoa, Enrique;
Palomo, Claudio

Publication type:

Article

A 4-Hydroxypyrrolidine-Catalyzed Mannich Reaction of Aldehydes: Control of anti-Selectivity by Hydrogen Bonding Assisted by Brønsted Acids.

Published in:

Chemistry - A European Journal, 2010, v. 16, n. 18, p. 5333, doi. 10.1002/chem.200903537

By:

Gómez-Bengoa, Enrique;
Maestro, Miguel;
Mielgo, Antonia;
Otazo, Itziar;
Palomo, Claudio;
Velilla, Irene

Publication type:

Article

Intramolecular Coupling of Allyl Carboxylates with Allyl Stannanes and Allyl Silanes: A New Type of Reductive Elimination Reaction?

Published in:

Chemistry - A European Journal, 2002, v. 8, n. 16, p. 3620, doi. 10.1002/1521-3765(20020816)8:16<3620::AID-CHEM3620>3.0.CO;2-P

By:

Méndez, María;
Cuerva, Juan M.;
Gómez-Bengoa, Enrique;
Cárdenas, Diego J.;
Echavarren, Antonio M.

Publication type:

Article

Unprecedented Multicomponent Organocatalytic Synthesis of Propargylic Esters via CO2 Activation.

Published in:

ChemCatChem, 2019, v. 11, n. 21, p. 5379, doi. 10.1002/cctc.201900207

By:

Papastavrou, Argyro T.;
Pauze, Martin;
Gómez‐Bengoa, Enrique;
Vougioukalakis, Georgios C.

Publication type:

Article

Deep Eutectic Solvent Compatible Metallic Catalysts: Cationic Pyridiniophosphine Ligands in Palladium Catalyzed Cross-Coupling Reactions.

Published in:

ChemCatChem, 2017, v. 9, n. 7, p. 1269, doi. 10.1002/cctc.201601544

By:

Marset, Xavier;
Khoshnood, Abbas;
Sotorríos, Lia;
Gómez‐Bengoa, Enrique;
Alonso, Diego A.;
Ramón, Diego J.

Publication type:

Article

The First Gold(III) Formate: Evidence for β-Hydride Elimination.

Published in:

Angewandte Chemie International Edition, 2017, v. 56, n. 42, p. 12862, doi. 10.1002/anie.201705557

By:

Kumar, Roopender;
Krieger, Jean-Philippe;
Gómez-Bengoa, Enrique;
Fox, Thomas;
Linden, Anthony;
Nevado, Cristina

Publication type:

Article

Enantioselective Michael Addition of Aldehydes to Maleimides Organocatalyzed by a Chiral Primary Amine-Salicylamide.

Published in:

Molecules, 2018, v. 23, n. 12, p. 3299, doi. 10.3390/molecules23123299

By:

Torregrosa-Chinillach, Alejandro;
Moragues, Adrien;
Pérez-Furundarena, Haritz;
Chinchilla, Rafael;
Gómez-Bengoa, Enrique;
Guillena, Gabriela

Publication type:

Article

Asymmetric Conjugate Addition of α,α-Disubstituted Aldehydes to Nitroalkenes Organocatalyzed by Chiral Monosalicylamides from trans-Cyclohexane-1,2-Diamines.

Published in:

Molecules, 2018, v. 23, n. 1, p. 141, doi. 10.3390/molecules23010141

By:

Martínez-Guillén, José R.;
Flores-Ferrándiz, Jesús;
Gómez, Cecilia;
Gómez-Bengoa, Enrique;
Chinchilla, Rafael

Publication type:

Article

An umpolung strategy to react catalytic enols with nucleophiles.

Published in:

Nature Communications, 2019, v. 10, n. 1, p. N.PAG, doi. 10.1038/s41467-019-13175-5

By:

Sanz-Marco, Amparo;
Martinez-Erro, Samuel;
Pauze, Martin;
Gómez-Bengoa, Enrique;
Martín-Matute, Belén

Publication type:

Article

Works by Gómez‐Bengoa, Enrique

Olefin Epoxidation Catalyzed by cis-Dioxdomolybdenum(VI) Complexes Containing Chiral Alkoxo-Imino Ligands Derived from (+)-α-Pinene.

Four‐Step Synthesis of (−)‐4‐epi‐Presilphiperfolan‐8α‐ol by Intramolecular Iron Hydride Atom Transfer‐Mediated Ketone‐Alkene Coupling and Studies to Access trans‐Hydrindanols with a Botryane Scaffold

An Expedient Method for the Umpolung Coupling of Enols with Heteronucleophiles**.

Synthesis of Cyclometalated Gold(III) Complexes via Catalytic Rhodium to Gold(III) Transmetalation.

Brønsted Base Catalyzed One‐Pot Synthesis of Stereodefined Six‐Member Carbocycles Featuring Transient Trienolates and a Key Intramolecular 1,6‐Addition.

Domino Reactions with Dicyanoalkenes and Fluorinated Conjugated Sulfinyl Imines. A Convenient Strategy for the Generation of Structural Diversity.

Manganese‐Catalyzed Multicomponent Synthesis of Tetrasubstituted Propargylamines: System Development and Theoretical Study.

N-(Diazoacetyl)oxazolidin-2-thiones as Sulfur-Donor Reagents: Asymmetric Synthesis of Thiiranes from Aldehydes.

Regio- and Enantioselective Direct Oxyamination Reaction of Aldehydes Catalyzed by α,α-Diphenylprolinol Trimethylsilyl Ether.

Synthesis of 3‐Amino‐1‐benzothiophene‐1,1‐diones by Alkyne Directed Hydroarylation and 1/N→3/C‐Sulfonyl Migration.

Annulated N-Heterocycles by Tandem Gold(I)-Catalyzed [3,3]-Rearrangement/Nazarov Reaction of Propargylic Ester Derivatives: an Experimental and Computational Study.

Gold-Catalysed Synthesis of Exocyclic Vinylogous Amides and β-Amino Ketones: A Detailed Study on the 5-exo/6-endo-dig Selectivity, Methodology and Scope.

Gold-Catalysed Synthesis of Exocyclic Vinylogous Amides and β-Amino Ketones: A Detailed Study on the 5- exo/6- endo- dig Selectivity, Methodology and Scope.

Pyrimidine-Derived Prolinamides as Recoverable Bifunctional Organocatalysts for Enantioselective Inter- and Intramolecular Aldol Reactions under Solvent-Free Conditions.

Solvent-Induced Reversal of Enantioselectivity in the Synthesis of Succinimides by the Addition of Aldehydes to Maleimides Catalysed by Carbamate-Monoprotected 1,2-Diamines.

Enantioselective Synthesis of Succinimides by Michael Addition of Aldehydes to Maleimides Organocatalyzed by Chiral Primary Amine-Guanidines.

Enantioselective Synthesis of Succinimides by Michael Addition of 1,3-Dicarbonyl Compounds to Maleimides Catalyzed by a Chiral Bis(2-aminobenzimidazole) Organocatalyst.

Synthesis of Cyclometalated Gold(III) Complexes via Catalytic Rhodium to Gold(III) Transmetalation.

Brønsted Base Catalyzed One‐Pot Synthesis of Stereodefined Six‐Member Carbocycles Featuring Transient Trienolates and a Key Intramolecular 1,6‐Addition.

α‐Branched Ketone Dienolates: Base‐Catalysed Generation and Regio‐ and Enantioselective Addition Reactions.

Synthetic and Mechanistic Investigation of an Oxime Ether Electrocyclization Approach to Heteroaromatic Boronic Acid Derivatives.

Expeditious diastereoselective synthesis of elaborated ketones via remote Csp<sup>3</sup>-H functionalization.

Directed C−H Allylation of Aromatic Carboxamides with Allyl Aryl Ethers under Cp*Co(III)‐Catalysis.

A Modular Class of Fluorescent Difluoroboranes: Synthesis, Structure, Optical Properties, Theoretical Calculations and Applications for Biological Imaging.

Gold-Catalyzed 1,2-/1,2-Bis-acetoxy Migration of 1,4-Bis-propargyl Acetates: A Mechanistic Study.

The First Gold(III) Formate: Evidence for β-Hydride Elimination.

N-(Diazoacetyl)oxazolidin-2-thiones as Sulfur-Donor Reagents: Asymmetric Synthesis of Thiiranes from Aldehydes.

Unravelling mechanistic insights in the platinum-catalysed dihydroalkoxylation of allenes.

Cationic Intermediates in the Intramolecular Insertion of Alkenes into (η<sup>3</sup>-Allyl)palladium( II) Complexes.

Brønsted Acid Assisted Regio- and Enantioselective Direct O-Nitroso Aldol Reaction Catalysed by α,α-Diphenylprolinol Trimethylsilyl Ether.

A 4-Hydroxypyrrolidine-Catalyzed Mannich Reaction of Aldehydes: Control of anti-Selectivity by Hydrogen Bonding Assisted by Brønsted Acids.

Intramolecular Coupling of Allyl Carboxylates with Allyl Stannanes and Allyl Silanes: A New Type of Reductive Elimination Reaction?

Unprecedented Multicomponent Organocatalytic Synthesis of Propargylic Esters via CO<sub>2</sub> Activation.

Deep Eutectic Solvent Compatible Metallic Catalysts: Cationic Pyridiniophosphine Ligands in Palladium Catalyzed Cross-Coupling Reactions.

The First Gold(III) Formate: Evidence for β-Hydride Elimination.

Enantioselective Michael Addition of Aldehydes to Maleimides Organocatalyzed by a Chiral Primary Amine-Salicylamide.

Asymmetric Conjugate Addition of α,α-Disubstituted Aldehydes to Nitroalkenes Organocatalyzed by Chiral Monosalicylamides from trans-Cyclohexane-1,2-Diamines.

An umpolung strategy to react catalytic enols with nucleophiles.