Works by Dewhurst, Rian D.

Results: 143

Electron‐Precise Dicationic Tetraboranes: Syntheses, Structures and Rearrangement to an Alkylidene Borate‐Borenium Zwitterion and a 1,3‐Azaborinine.

Published in:

Chemistry - A European Journal, 2023, v. 29, n. 45, p. 1, doi. 10.1002/chem.202300644

By:

Lu, Wei;
Hensiek, Nicola;
Saha, Koushik;
Dewhurst, Rian D.;
Härterich, Marcel;
Pranckevicius, Conor;
Hagspiel, Stephan;
Dietz, Maximilian;
Krummenacher, Ivo;
Braunschweig, Holger

Publication type:

Article

Thienyl‐Substituted Diboranes(4): Electronic Stabilization of Radicals Versus Increased Reactivity towards Bond Activation.

Published in:

Chemistry - A European Journal, 2023, v. 29, n. 40, p. 1, doi. 10.1002/chem.202301286

By:

Schorr, Fabian;
Keim, Timo;
Arrowsmith, Merle;
Vargas, Alfredo;
Dewhurst, Rian D.;
Krummenacher, Ivo;
Braunschweig, Holger

Publication type:

Article

Reduktive Borylen-CO-Kupplung an einem sterisch anspruchsvollen Arylborylenkomplex.

Published in:

Angewandte Chemie, 2013, v. 125, n. 38, p. 10307, doi. 10.1002/ange.201303798

By:

Braunschweig, Holger;
Dewhurst, Rian D.;
Hörl, Christian;
Radacki, Krzysztof;
Tate, Christopher W.;
Vargas, Alfredo;
Ye, Qing

Publication type:

Article

Einfach-, Doppel-, Dreifachbindungen und Ketten: Knüpfung elektronenpräziser B-B-Bindungen.

Published in:

Angewandte Chemie, 2013, v. 125, n. 13, p. 3658, doi. 10.1002/ange.201208189

By:

Braunschweig, Holger;
Dewhurst, Rian D.

Publication type:

Article

Maximierung von koordinativer und elektronischer Ungesättigtheit: dreifach koordinierte dikationische Platinkomplexe.

Published in:

Angewandte Chemie, 2013, v. 125, n. 10, p. 3055, doi. 10.1002/ange.201209717

By:

Braunschweig, Holger;
Brenner, Peter;
Dewhurst, Rian D.;
Jimenez ‐ Halla, J. Oscar C.;
Kupfer, Thomas;
Rais, Daniela;
Uttinger, Katharina

Publication type:

Article

Ein planar vierfach koordiniertes Boratom als Ligand für vier Metalle.

Published in:

Angewandte Chemie, 2012, v. 124, n. 9, p. 2225, doi. 10.1002/ange.201107248

By:

Braunschweig, Holger;
Dewhurst, Rian D.;
Kraft, Katharina;
Östreicher, Sebastian;
Radacki, Krzysztof

Publication type:

Article

Spät aber mit Stil: Synthese und Charakterisierung der ersten Übergangsmetall-Fluorborylenkomplexe.

Published in:

Angewandte Chemie, 2010, v. 122, n. 20, p. 3486, doi. 10.1002/ange.201000841

By:

Braunschweig, Holger;
Dewhurst, Rian D.

Publication type:

Article

Ein linearer anionischer Dimetallborylenkomplex.

Published in:

Angewandte Chemie, 2008, v. 120, n. 30, p. 5732, doi. 10.1002/ange.200801848

By:

Braunschweig, Holger;
Burzler, Michael;
Dewhurst, Rian D.;
Radacki, Krzysztof

Publication type:

Article

Towards the catalytic activation of inert small molecules by main-group ambiphiles.

Published in:

Communications Chemistry, 2020, v. 3, n. 1, p. N.PAG, doi. 10.1038/s42004-020-00371-4

By:

Dewhurst, Rian D.;
Légaré, Marc-André;
Braunschweig, Holger

Publication type:

Article

A step-for-step main-group replica of the Fischer carbene synthesis at a borylene carbonyl.

Published in:

Nature Communications, 2023, v. 14, n. 1, p. 1, doi. 10.1038/s41467-023-36251-3

By:

Härterich, Marcel;
Matler, Alexander;
Dewhurst, Rian D.;
Sachs, Andreas;
Oppel, Kai;
Stoy, Andreas;
Braunschweig, Holger

Publication type:

Article

All‐Inorganic sp‐Chain Ligands: Isoelectronic B/N Analogues of E. O. Fischer's Alkynylcarbynes.

Published in:

Angewandte Chemie International Edition, 2024, v. 63, n. 30, p. 1, doi. 10.1002/anie.202404930

By:

Walther, Luis;
Radacki, Krzysztof;
Dewhurst, Rian D.;
Bertermann, Rüdiger;
Finze, Maik;
Braunschweig, Holger

Publication type:

Article

Bypassing Ammonia: From N2 to Nitrogen Heterocycles without N1 Intermediates or Transition Metals.

Published in:

Angewandte Chemie International Edition, 2024, v. 63, n. 21, p. 1, doi. 10.1002/anie.202402777

By:

Weber, Marco;
Kupfer, Thomas;
Arrowsmith, Merle;
Dewhurst, Rian D.;
Rang, Maximilian;
Ritschel, Benedikt;
Titlbach, Sven;
Ernst, Martin;
Rodrigues, Marieli O.;
da Silva Júnior, Eufrânio N.;
Braunschweig, Holger

Publication type:

Article

Synthesis and Reactivity of a Dialane‐Bridged Diradical.

Published in:

Angewandte Chemie International Edition, 2024, v. 63, n. 18, p. 1, doi. 10.1002/anie.202401052

By:

Dhara, Debabrata;
Endres, Lukas;
Krummenacher, Ivo;
Arrowsmith, Merle;
Dewhurst, Rian D.;
Engels, Bernd;
Bertermann, Rüdiger;
Finze, Maik;
Demeshko, Serhiy;
Meyer, Franc;
Fantuzzi, Felipe;
Braunschweig, Holger

Publication type:

Article

Metal‐Free Intermolecular C−H Borylation of N‐Heterocycles at B−B Multiple Bonds.

Published in:

Angewandte Chemie International Edition, 2023, v. 62, n. 5, p. 1, doi. 10.1002/anie.202213284

By:

Brückner, Tobias;
Ritschel, Benedikt;
Jiménez‐Halla, J. Oscar C.;
Fantuzzi, Felipe;
Duwe, Dario;
Markl, Christian;
Dewhurst, Rian D.;
Dietz, Maximilian;
Braunschweig, Holger

Publication type:

Article

An Unsymmetrical, Cyclic Diborene Based on a Chelating CAAC Ligand and its Small‐Molecule Activation and Rearrangement Chemistry.

Published in:

Angewandte Chemie International Edition, 2022, v. 61, n. 3, p. 1, doi. 10.1002/anie.202113947

By:

Lu, Wei;
Jayaraman, Arumugam;
Fantuzzi, Felipe;
Dewhurst, Rian D.;
Härterich, Marcel;
Dietz, Maximilian;
Hagspiel, Stephan;
Krummenacher, Ivo;
Hammond, Kai;
Cui, Jingjing;
Braunschweig, Holger

Publication type:

Article

Adducts of the Parent Boraphosphaketene H2BPCO and their Decarbonylative Insertion Chemistry.

Published in:

Angewandte Chemie International Edition, 2021, v. 60, n. 24, p. 13666, doi. 10.1002/anie.202103521

By:

Hagspiel, Stephan;
Fantuzzi, Felipe;
Dewhurst, Rian D.;
Gärtner, Annalena;
Lindl, Felix;
Lamprecht, Anna;
Braunschweig, Holger

Publication type:

Article

Isolation of Neutral, Mono‐, and Dicationic B2P2 Rings by Diphosphorus Addition to a Boron−Boron Triple Bond.

Published in:

Angewandte Chemie International Edition, 2021, v. 60, n. 24, p. 13661, doi. 10.1002/anie.202102218

By:

Brückner, Tobias;
Fantuzzi, Felipe;
Stennett, Tom E.;
Krummenacher, Ivo;
Dewhurst, Rian D.;
Engels, Bernd;
Braunschweig, Holger

Publication type:

Article

Isolation and Reactivity of an Antiaromatic s‐Block Metal Compound.

Published in:

Angewandte Chemie International Edition, 2021, v. 60, n. 7, p. 3812, doi. 10.1002/anie.202014557

By:

Roy, Dipak Kumar;
Tröster, Tobias;
Fantuzzi, Felipe;
Dewhurst, Rian D.;
Lenczyk, Carsten;
Radacki, Krzysztof;
Pranckevicius, Conor;
Engels, Bernd;
Braunschweig, Holger

Publication type:

Article

Boron: Its Role in Energy‐Related Processes and Applications.

Published in:

Angewandte Chemie International Edition, 2020, v. 59, n. 23, p. 8800, doi. 10.1002/anie.201911108

By:

Huang, Zhenguo;
Wang, Suning;
Dewhurst, Rian D.;
Ignat'ev, Nikolai V.;
Finze, Maik;
Braunschweig, Holger

Publication type:

Article

Tetraiododiborane(4) (B2I4) is a Polymer Based on sp3 Boron in the Solid State.

Published in:

Angewandte Chemie International Edition, 2020, v. 59, n. 14, p. 5531, doi. 10.1002/anie.201913590

By:

Muessig, Jonas H.;
Lisinetskaya, Polina;
Dewhurst, Rian D.;
Bertermann, Rüdiger;
Thaler, Melanie;
Mitrić, Roland;
Braunschweig, Holger

Publication type:

Article

Heterobimetallic C3 Complexes through Silylpropargylidyne Desilylation.

Published in:

Angewandte Chemie, 2004, v. 116, n. 4, p. 482, doi. 10.1002/ange.200352693

By:

Rian D. Dewhurst;
Anthony F. Hill;
Matthew K. Smith

Publication type:

Article

Does Lewis basicity correlate with catalytic performance in zerovalent group 8 complexes?

Published in:

Zeitschrift für Naturforschung B: A Journal of Chemical Sciences, 2018, v. 73, n. 3/4, p. 149, doi. 10.1515/znb-2017-0193

By:

Braunschweig, Holger;
Brunecker, Carina;
Dewhurst, Rian D.;
Schneider, Christoph

Publication type:

Article

Does Lewis basicity correlate with catalytic performance in zerovalent group 8 complexes?

Published in:

Zeitschrift für Naturforschung B: A Journal of Chemical Sciences, 2018, p. 149, doi. 10.1515/znb-2017-0193

By:

Braunschweig, Holger;
Brunecker, Carina;
Dewhurst, Rian D.;
Schneider, Christoph

Publication type:

Article

Isolation of diborenes and their 90°-twisted diradical congeners.

Published in:

Nature Communications, 2018, v. 9, n. 1, p. 1, doi. 10.1038/s41467-018-02998-3

By:

Böhnke, Julian;
Dellermann, Theresa;
Celik, Mehmet Ali;
Krummenacher, Ivo;
Dewhurst, Rian D.;
Demeshko, Serhiy;
Ewing, William C.;
Hammond, Kai;
Heß, Merlin;
Bill, Eckhard;
Welz, Eileen;
Röhr, Merle I. S.;
Mitrić, Roland;
Engels, Bernd;
Meyer, Franc;
Braunschweig, Holger

Publication type:

Article

Building Electron-Precise BoronBoron Single Bonds: Imposing Monogamy on a Promiscuous Element.

Published in:

ChemCatChem, 2015, v. 7, n. 11, p. 1630, doi. 10.1002/cctc.201500219

By:

Braunschweig, Holger;
Dewhurst, Rian D.;
Mozo, Silvia

Publication type:

Article

DFT Study on Alkyl- and Haloborylene Complexes of Manganese and Rhenium: Structure and Bonding Energy Analysis in [(η.

Published in:

European Journal of Inorganic Chemistry, 2011, v. 2011, n. 13, p. 2045, doi. 10.1002/ejic.201001200

By:

Pandey, Krishna K.;
Braunschweig, Holger;
Dewhurst, Rian D.

Publication type:

Article

Phosphine‐Stabilized Diiododiborenes: Isolable Diborenes with Six Labile Bonds.

Published in:

Angewandte Chemie International Edition, 2019, v. 58, n. 13, p. 4405, doi. 10.1002/anie.201814230

By:

Muessig, Jonas H.;
Thaler, Melanie;
Dewhurst, Rian D.;
Paprocki, Valerie;
Seufert, Jens;
Mattock, James D.;
Vargas, Alfredo;
Braunschweig, Holger

Publication type:

Article

A New Perspective on Borane Chemistry: The Nucleophilicity of the B−H Bonding Pair Electrons.

Published in:

Angewandte Chemie International Edition, 2019, v. 58, n. 11, p. 3268, doi. 10.1002/anie.201809733

By:

Zhao, Qianyi;
Dewhurst, Rian D.;
Braunschweig, Holger;
Chen, Xuenian

Publication type:

Article

A New Class of Neutral Boron‐Based Diradicals Spanned by a Two‐Carbon‐Atom Bridge.

Published in:

Angewandte Chemie International Edition, 2019, v. 58, n. 6, p. 1842, doi. 10.1002/anie.201813335

By:

Deissenberger, Andrea;
Welz, Eileen;
Drescher, Regina;
Krummenacher, Ivo;
Dewhurst, Rian D.;
Engels, Bernd;
Braunschweig, Holger

Publication type:

Article

Isolation and Characterization of Crystalline, Neutral Diborane(4) Radicals.

Published in:

Angewandte Chemie International Edition, 2018, v. 57, n. 33, p. 10752, doi. 10.1002/anie.201804048

By:

Seufert, Jens;
Welz, Eileen;
Krummenacher, Ivo;
Paprocki, Valerie;
Böhnke, Julian;
Hagspiel, Stephan;
Dewhurst, Rian D.;
Tacke, Reinhold;
Engels, Bernd;
Braunschweig, Holger

Publication type:

Article

Diboryldiborenes: π‐Conjugated B4 Chains Isoelectronic to the Butadiene Dication.

Published in:

Angewandte Chemie International Edition, 2018, v. 57, n. 32, p. 10091, doi. 10.1002/anie.201805394

By:

Hermann, Alexander;
Cid, Jessica;
Mattock, James D.;
Dewhurst, Rian D.;
Krummenacher, Ivo;
Vargas, Alfredo;
Ingleson, Michael J.;
Braunschweig, Holger

Publication type:

Article

Bottleable Neutral Analogues of [B2H5]− as Versatile and Strongly Binding η2 Donor Ligands.

Published in:

Angewandte Chemie International Edition, 2018, v. 57, n. 21, p. 6347, doi. 10.1002/anie.201801722

By:

Wang, Sunewang R.;
Prieschl, Dominic;
Mattock, James D.;
Arrowsmith, Merle;
Pranckevicius, Conor;
Stennett, Tom E.;
Dewhurst, Rian D.;
Vargas, Alfredo;
Braunschweig, Holger

Publication type:

Article

CO2 Binding and Splitting by Boron–Boron Multiple Bonds.

Published in:

Angewandte Chemie International Edition, 2018, v. 57, n. 20, p. 5947, doi. 10.1002/anie.201802117

By:

Stoy, Andreas;
Böhnke, Julian;
Jiménez‐Halla, J. Oscar C.;
Dewhurst, Rian D.;
Thiess, Torsten;
Braunschweig, Holger

Publication type:

Article

Transition-Metal π-Ligation of a Tetrahalodiborane.

Published in:

Angewandte Chemie International Edition, 2018, v. 57, n. 2, p. 412, doi. 10.1002/anie.201709515

By:

Braunschweig, Holger;
Dewhurst, Rian D.;
Jiménez‐Halla, J. Oscar C.;
Matito, Eduard;
Muessig, Jonas H.

Publication type:

Article

Synthesis and Trapping of Iminoboranes by M=B/C=N Bond Metathesis.

Published in:

Angewandte Chemie International Edition, 2017, v. 56, n. 27, p. 7975, doi. 10.1002/anie.201703324

By:

Nutz, Marco;
Borthakur, Bitupon;
Dewhurst, Rian D.;
Deißenberger, Andrea;
Dellermann, Theresa;
Schäfer, Marius;
Krummenacher, Ivo;
Phukan, Ashwini K.;
Braunschweig, Holger

Publication type:

Article

Engineering a Small HOMO-LUMO Gap and Intramolecular C−H Borylation by Diborene/Anthracene Orbital Intercalation.

Published in:

Angewandte Chemie International Edition, 2017, v. 56, n. 27, p. 8009, doi. 10.1002/anie.201704063

By:

Wang, Sunewang R.;
Arrowsmith, Merle;
Böhnke, Julian;
Braunschweig, Holger;
Dellermann, Theresa;
Dewhurst, Rian D.;
Kelch, Hauke;
Krummenacher, Ivo;
Mattock, James D.;
Müssig, Jonas H.;
Thiess, Torsten;
Vargas, Alfredo;
Zhang, Jiji

Publication type:

Article

Generation of Dicoordinate Boron(I) Units by Fragmentation of a Tetra-Boron(I) Molecular Square.

Published in:

Angewandte Chemie International Edition, 2016, v. 55, n. 46, p. 14464, doi. 10.1002/anie.201608429

By:

Arrowsmith, Merle;
Auerhammer, Dominic;
Bertermann, Rüdiger;
Braunschweig, Holger;
Celik, Mehmet Ali;
Dewhurst, Rian D.;
Finze, Maik;
Hailmann, Michael;
Hertle, Thomas;
Krummenacher, Ivo;
Bringmann, Gerhard;
Grüne, Matthias

Publication type:

Article

Two-Dimensional, but not Flat: An All-Boron Graphene with a Corrugated Structure.

Published in:

Angewandte Chemie International Edition, 2016, v. 55, n. 16, p. 4866, doi. 10.1002/anie.201601463

By:

Dewhurst, Rian D.;
Claessen, Ralph;
Braunschweig, Holger

Publication type:

Article

Mild and Complete Carbonyl Ligand Scission on a Mononuclear Transition Metal Complex.

Published in:

Angewandte Chemie International Edition, 2016, v. 55, n. 16, p. 5076, doi. 10.1002/anie.201600307

By:

Braunschweig, Holger;
Celik, Mehmet Ali;
Dewhurst, Rian D.;
Kachel, Stephanie;
Wennemann, Benedikt

Publication type:

Article

Dative Bonding between Group 13 Elements Using a Boron-Centered Lewis Base.

Published in:

Angewandte Chemie International Edition, 2016, v. 55, n. 1, p. 436, doi. 10.1002/anie.201509289

By:

Braunschweig, Holger;
Dewhurst, Rian D.;
Pentecost, Leanne;
Radacki, Krzysztof;
Vargas, Alfredo;
Ye, Qing

Publication type:

Article

Exclusive π Encapsulation of Light Alkali Metal Cations by a Neutral Molecule.

Published in:

Angewandte Chemie International Edition, 2015, v. 54, n. 44, p. 13090, doi. 10.1002/anie.201506487

By:

Bertermann, Rüdiger;
Braunschweig, Holger;
Constantinidis, Philipp;
Dellermann, Theresa;
Dewhurst, Rian D.;
Ewing, William C.;
Fischer, Ingo;
Kramer, Thomas;
Mies, Jan;
Phukan, Ashwini K.;
Vargas, Alfredo

Publication type:

Article

Cyclization of a 1,4-Diborabutadiene Ligand with Both Atoms of CO.

Published in:

Angewandte Chemie International Edition, 2015, v. 54, n. 17, p. 5065, doi. 10.1002/anie.201411967

By:

Braunschweig, Holger;
Ye, Qing;
Celik, Mehmet Ali;
Dewhurst, Rian D.;
Radacki, Krzysztof

Publication type:

Article

Unexpected Luminescence Behavior of Coinage Metal π-Diborene Complexes.

Published in:

Angewandte Chemie International Edition, 2015, v. 54, n. 14, p. 4362, doi. 10.1002/anie.201408993

By:

Bissinger, Philipp;
Steffen, Andreas;
Vargas, Alfredo;
Dewhurst, Rian D.;
Damme, Alexander;
Braunschweig, Holger

Publication type:

Article

Trihapto Ligation of a Borirene to a Single Metal Atom: A Heterocyclic Analogue of the η3-Cyclopropenyl Ligand.

Published in:

Angewandte Chemie International Edition, 2014, v. 53, n. 24, p. 6263, doi. 10.1002/anie.201402815

By:

Braunschweig, Holger;
Dewhurst, Rian D.;
Radacki, Krzysztof;
Tate, Christopher W.;
Vargas, Alfredo

Publication type:

Article

Evidence for Extensive Single-Electron-Transfer Chemistry in Boryl Anions: Isolation and Reactivity of a Neutral Borole Radical.

Published in:

Angewandte Chemie International Edition, 2014, v. 53, n. 21, p. 5453, doi. 10.1002/anie.201402556

By:

Bertermann, Rüdiger;
Braunschweig, Holger;
Dewhurst, Rian D.;
Hörl, Christian;
Kramer, Thomas;
Krummenacher, Ivo

Publication type:

Article

Inside Back Cover: Evidence for Extensive Single-Electron-Transfer Chemistry in Boryl Anions: Isolation and Reactivity of a Neutral Borole Radical (Angew. Chem. Int. Ed. 21/2014).

Published in:

Angewandte Chemie International Edition, 2014, v. 53, n. 21, p. 5473, doi. 10.1002/anie.201403558

By:

Bertermann, Rüdiger;
Braunschweig, Holger;
Dewhurst, Rian D.;
Hörl, Christian;
Kramer, Thomas;
Krummenacher, Ivo

Publication type:

Article

Metal-Only Lewis Pairs by Reversible Insertion of Ruthenium and Osmium Fragments into Metal-Boron Double Bonds.

Published in:

Angewandte Chemie International Edition, 2014, v. 53, n. 16, p. 4240, doi. 10.1002/anie.201310520

By:

Bertsch, Stefanie;
Bertermann, Rüdiger;
Braunschweig, Holger;
Damme, Alexander;
Dewhurst, Rian D.;
Phukan, Ashwini K.;
Saalfrank, Christian;
Vargas, Alfredo;
Wennemann, Benedikt;
Ye, Qing

Publication type:

Article

Direct Hydroboration of BB Bonds: A Mild Strategy for the Proliferation of BB Bonds.

Published in:

Angewandte Chemie International Edition, 2014, v. 53, n. 12, p. 3241, doi. 10.1002/anie.201309325

By:

Braunschweig, Holger;
Dewhurst, Rian D.;
Hörl, Christian;
Phukan, Ashwini K.;
Pinzner, Florian;
Ullrich, Stefan

Publication type:

Article

Reductive Borylene-CO Coupling with a Bulky Arylborylene Complex.

Published in:

Angewandte Chemie International Edition, 2013, v. 52, n. 38, p. 10120, doi. 10.1002/anie.201303798

By:

Braunschweig, Holger;
Dewhurst, Rian D.;
Hörl, Christian;
Radacki, Krzysztof;
Tate, Christopher W.;
Vargas, Alfredo;
Ye, Qing

Publication type:

Article

π‐Complexes of Diborynes with Main Group Atoms.

Published in:

Chemistry - An Asian Journal, 2020, v. 15, n. 10, p. 1553, doi. 10.1002/asia.202000185

By:

Ewing, William C.;
Dellermann, Theresa;
Angel Wong, Y. T.;
Mattock, James D.;
Vargas, Alfredo;
Bryce, David L.;
Dewhurst, Rian D.;
Braunschweig, Holger

Publication type:

Article