Title

Synthesis of aryl-containing terpenoids based on 1,4-dihydronaphthalene.

Authors

Kukovinets, O. S.; Kislitsyn, M. I.; Zainullin, R. A.; Mukhamedzyanova, A. A.; Galin, F. Z.; Abdullin, M. I.

Abstract

Successive transformations including oxidation of 1,4-dihydronaphthalene into 1,2,3,4-tetrahydronaphthalen-2-one, Reformatskii reaction of the latter with methyl bromoacetate, ozonolysis of the Reformatsky reaction product, and Emmons olefination of the aldehyde group in methyl 3-oxo-5-(2-formylphenyl)pentanate thus formed gave analogs of highly active dienoate juvenoids having an aromatic ring in their molecules.

Subjects

ORGANIC compounds; OXIDATION; OZONOLYSIS; MOLECULES; OZONE; TERPENES

Publication

Russian Journal of Organic Chemistry, 2008, Vol 44, Issue 3, p362

ISSN

1070-4280

Publication type

Academic Journal

DOI

10.1134/S1070428008030093