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- Title
Towards recyclable NAD(P)H regeneration catalysts.
- Authors
de Torres, Miriam; Dimroth, Jonas; Arends, Isabel W C E; Keilitz, Juliane; Hollmann, Frank
- Abstract
Rh(III)-TsDPEN, an immobilized analog of the well-known [Cp*Rh(bpy)(H(2)O)](2+) was evaluated as a heterogeneous, recyclable regeneration catalyst for reduced oxidoreductase cofactors [NAD(P)H]. Repeated use of this catalyst was established and the catalytic properties were initially investigated. Apparently, Rh(III)-TsDPEN is prone to severe diffusion limitations, necessitating further developments. Overall, a promising concept for chemoenzymatic redox catalysis is proposed, which may overcome some of the current limitations such as catalyst cost and incompatibility of Rh with some biocatalysts.
- Publication
Molecules (Basel, Switzerland), 2012, Vol 17, Issue 8, p9835
- ISSN
1420-3049
- Publication type
Journal Article
- DOI
10.3390/molecules17089835