Recent advances in synthesis of organometallic complexes of indium.

Anwar, Hira; Haque, Rosenani A.; Saleem, Rahman Shah Zaib; Iqbal, Muhammad Adnan

The indium complexes are being used in many applications like catalysis, optoelectronics, sensors, solar cells, biochemistry, medicine, infrared (IR) mirrors and thin-film transistors (TFTs). In organometallic complexes of indium, it forms different types of complexes with single, double, triple and tetra linkages by coordinating with numerous elements like C, N, O and S and also with some other elements like Se and Ru. So, the present study comprises all the possible ways to synthesize the indium complexes by reacting with different organic ligands; most of them are N-heterocyclic carbenes, amines, amides and phenols. The commonly used solvents for these syntheses are tetrahydrofuran, dichloromethane, toluene, benzene, dimethyl sulfoxide (DMSO) and water. According to the nature of the ligands, indium complexes were reported at different temperatures and stirring time. Because of their unique characteristics, the organometallic chemistry of group 13 metal indium complexes remains a subject of continuing interest in synthetic chemistry as well as material science.

INDIUM; MATERIALS science; DIMETHYL sulfoxide; TETRAHYDROFURAN synthesis; ORGANOMETALLIC chemistry; INDIUM oxide; TOLUENE

Reviews in Inorganic Chemistry, 2020, Vol 40, Issue 3, p107

0193-4929

Academic Journal

10.1515/revic-2020-0005