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Title: Reverse micellar catalysis of phosphorylation of pyrimidinophanes.
Authors: Zhil'tsova, E.; Kudryavtseva, L.; Mikhailov, A.; Semenov, V.; Reznik, V.; Konovalov, A.
Abstract: The reaction of pyrimidinophanes with 4-nitrophenyl bis(chloromethyl)phosphinate in reverse micellar solutions of cetyltrimethylammonium bromide, polyethylene glycol 600 monolaurate, and their mixture was studied by spectrophotometry in chloroform. The catalytic activity of the micelles was found to depend on the macrocycle size and concentration and relative content of surfactants in the solution.
Subjects: ORGANONITROGEN compounds; REVERSED micelles; CATALYSIS; PHOSPHORYLATION; ORGANOPHOSPHORUS compounds; AMMONIUM compounds; SPECTROPHOTOMETRY; SURFACE active agents
Publication: Russian Journal of General Chemistry, 2008, Vol 78, Issue 1, p50
ISSN: 1070-3632
Publication type: Academic Journal
DOI: 10.1134/S107036320801009X

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Reverse micellar catalysis of phosphorylation of pyrimidinophanes.