Title

Reverse micellar catalysis of phosphorylation of pyrimidinophanes.

Authors

Zhil'tsova, E.; Kudryavtseva, L.; Mikhailov, A.; Semenov, V.; Reznik, V.; Konovalov, A.

Abstract

The reaction of pyrimidinophanes with 4-nitrophenyl bis(chloromethyl)phosphinate in reverse micellar solutions of cetyltrimethylammonium bromide, polyethylene glycol 600 monolaurate, and their mixture was studied by spectrophotometry in chloroform. The catalytic activity of the micelles was found to depend on the macrocycle size and concentration and relative content of surfactants in the solution.

Subjects

ORGANONITROGEN compounds; REVERSED micelles; CATALYSIS; PHOSPHORYLATION; ORGANOPHOSPHORUS compounds; AMMONIUM compounds; SPECTROPHOTOMETRY; SURFACE active agents

Publication

Russian Journal of General Chemistry, 2008, Vol 78, Issue 1, p50

ISSN

1070-3632

Publication type

Academic Journal

DOI

10.1134/S107036320801009X