Title

Kinetics of α-olefin metathesis over the heterogeneous catalytic system (MoOCl/SiO)-SnMe.

Authors

Bykov, V.; Belyaev, B.; Butenko, T.; Finkelshtein, E.

Abstract

The kinetics of 1-hexene and 1-octene metathesis over the (MoOC/SiO)-SnMe catalytic system at 27 and 50°C has been investigated. The rate constants of the forward and reverse reactions and the catalyst deactivation constants have been measured. The number of active sites has been determined to be 10-13 mol % of the total number of molybdenum atoms.

Subjects

ALKENES; METATHESIS reactions; HETEROGENEOUS catalysis; CHEMICAL kinetics; TIN compounds; CHEMICAL reactions; CATALYST poisoning

Publication

Kinetics & Catalysis, 2012, Vol 53, Issue 3, p353

ISSN

0023-1584

Publication type

Academic Journal

DOI

10.1134/S0023158412030056