Title: Polarity and Structure of Silatranes with Planar Fragments.
Authors: Ishmaeva, Eleonora A.; Timosheva, Alina P.; Gazizova, Aisylu A.; Chachkov, Denis V.; Vereshchagina, Yana A.; Kataev, Vladimir E.; Timosheva, Natalya V.
Abstract: The structure of silatranes N[CH2(RMeC6H2)O]3SiR1 with planar fragments in six-membered semi-rings was established by the methods of dipole moments and density functional theory calculations. They are endo-structures with transannular interaction N → Si in which the oxygen atoms located adjacent to the silicon participate besides the nitrogen and silicon atoms.
Subjects: DENSITY functionals; DIPOLE moments; NITROGEN; SILICON; PHYSICAL & theoretical chemistry
Publication: Phosphorus, Sulfur & Silicon & the Related Elements, 2009, Vol 184, Issue 6, p1406
ISSN: 1042-6507
Publication type: Academic Journal
DOI: 10.1080/10426500902947500

Polarity and Structure of Silatranes with Planar Fragments.

Ishmaeva, Eleonora A.; Timosheva, Alina P.; Gazizova, Aisylu A.; Chachkov, Denis V.; Vereshchagina, Yana A.; Kataev, Vladimir E.; Timosheva, Natalya V.