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Title: Nickel‐Copper‐Catalyzed Hydroacylation of Vinylarenes with Acyl Fluorides and Hydrosilanes.
Authors: Ueda, Yusuke; Iwai, Tomohiro; Sawamura, Masaya
Abstract: The hydroacylation of vinylarenes with acyl fluorides and hydrosilanes was enabled by a synergistic bimetallic Ni/Cu‐catalytic system, giving access to the corresponding branched ketone products. The reaction takes place under mild conditions at 25–80 °C and tolerates base‐sensitive functional groups such as methoxycarbonyl and acetoxy groups.
Subjects: FUNCTIONAL groups; FLUORIDES
Publication: Chemistry - A European Journal, 2019, Vol 25, Issue 40, p9410
ISSN: 0947-6539
Publication type: Academic Journal
DOI: 10.1002/chem.201900822

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Nickel‐Copper‐Catalyzed Hydroacylation of Vinylarenes with Acyl Fluorides and Hydrosilanes.