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- Title
Diversity-oriented enantioselective synthesis of highly functionalized cyclic and bicyclic alcohols.
- Authors
Mao, Bin; Fañanás-Mastral, Martín; Lutz, Martin; Feringa, Ben L
- Abstract
The copper-catalyzed hetero-allylic asymmetric alkylation (h-AAA) of functionalized Grignard reagents that contain alkene or alkyne moieties has been achieved with excellent regio- and enantioselectivity. The corresponding alkylation products were further transformed into a variety of highly functionalized cyclic and bicyclic alcohols with excellent control over the chemo-, regio-, and stereoselectivity.
- Publication
Chemistry (Weinheim an der Bergstrasse, Germany), 2013, Vol 19, Issue 2, p761
- ISSN
1521-3765
- Publication type
Journal Article
- DOI
10.1002/chem.201202859