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- Title
Protonation-triggered generation of acylcobalt species from alkyne-[Co2(CO)6] complexes and their reaction with alkenes.
- Authors
Ooi, Isao; Sakurai, Takafumi; Takaya, Jun; Iwasawa, Nobuharu
- Abstract
An efficient protocol for the generation of acylcobalt species from alkyne-[Co(2)(CO)(6)] complexes is realized by treatment of the complexes with AcOH and pyridine. The generated acylcobalt species smoothly underwent addition reactions with various alkenes to give alkyl alkenyl ketones in good yield.
- Publication
Chemistry (Weinheim an der Bergstrasse, Germany), 2012, Vol 18, Issue 46, p14618
- ISSN
1521-3765
- Publication type
Journal Article
- DOI
10.1002/chem.201202749