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- Title
Selective construction of Pd2Pt and PdPt2 triangles in a sandwich framework: carbocyclic ligands as scaffolds for a mixed-metal system.
- Authors
Murahashi, Tetsuro; Usui, Kentaro; Tachibana, Yuki; Kimura, Seita; Ogoshi, Sensuke
- Abstract
Sandwich time! The mixed-metal triangular-trinuclear sandwich complexes of Pd(2)Pt and PdPt(2) were selectively synthesized. The Pd(2)Pt and PdPt(2) triangles in a cycloheptatrienyl sandwich framework were identified by (31)P NMR analyses of the tris-triphenylphosphine complexes (see scheme).
- Publication
Chemistry (Weinheim an der Bergstrasse, Germany), 2012, Vol 18, Issue 29, p8886
- ISSN
1521-3765
- Publication type
Journal Article
- DOI
10.1002/chem.201201474