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- Title
Stereoselective Synthesis of Vinyl Triflones and Heteroaryl Triflones through Anionic O→C<sub>vinyl</sub> and N→C<sub>vinyl</sub> Trifluoromethanesulfonyl Migration Reactions.
- Authors
Xu, Xiu‐Hua; Taniguchi, Misaki; Wang, Xin; Tokunaga, Etsuko; Ozawa, Tomohiro; Masuda, Hideki; Shibata, Norio
- Abstract
Six transformations, one pot: Various di‐ and trisubstituted vinyl triflones, as well as several heteroaryl triflones, were stereoselectively synthesized from easily accessible gem‐dibromovinyl substrates (see scheme, Boc=tert‐butoxycarbonyl). The highlights of this synthetic method lie in the remote O→Cvinyl or N→Cvinyl triflyl migrations and the one‐pot, three‐step protocol.
- Publication
Angewandte Chemie International Edition, 2013, Vol 52, Issue 48, p12628
- ISSN
1433-7851
- Publication type
Academic Journal
- DOI
10.1002/anie.201307535