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- Title
X-ray transient absorption and picosecond IR spectroscopy of fulvalene(tetracarbonyl)diruthenium on photoexcitation.
- Authors
Harpham, Michael R; Nguyen, Son C; Hou, Zongrui; Grossman, Jeffrey C; Harris, Charles B; Mara, Michael W; Stickrath, Andrew B; Kanai, Yosuke; Kolpak, Alexie M; Lee, Donghwa; Liu, Di-Jia; Lomont, Justin P; Moth-Poulsen, Kasper; Vinokurov, Nikolai; Chen, Lin X; Vollhardt, K Peter C
- Abstract
Caught in the light: The fulvalene diruthenium complex shown on the left side of the picture captures sun light, causing initial Ru-Ru bond rupture to furnish a long-lived triplet biradical of syn configuration. This species requires thermal activation to reach a crossing point (middle) into the singlet manifold on route to its thermal storage isomer on the right through the anti biradical.
- Publication
Angewandte Chemie (International ed. in English), 2012, Vol 51, Issue 31, p7692
- ISSN
1521-3773
- Publication type
Journal Article
- DOI
10.1002/anie.201202952