Title

Hybridization of Emerging Crystalline Porous Materials: Synthesis Dimensionality and Electrochemical Energy Storage Application.

Authors

Zhang, Huanhuan; Gu, Cheng; Yao, Ming‐Shui; Kitagawa, Susumu

Abstract

Metal–organic frameworks (MOFs) and covalent organic frameworks (COFs) are important members of crystalline porous materials due to their huge structural diversity and tunability. By hybridizing MOFs or COFs with other materials, restrictions of the pristine materials, i.e., poor conductivity and weak mechanical property, can be effectively circumvented. This review summarizes several hybridization techniques from the molecular level to the micro‐ and macroscales for the preparation of various MOF and COF hybrids. Then, their representative applications as electrochemical energy storage devices are elaborated, such as rechargeable batteries, supercapacitors, polymer electrolytes, and separators. The basic principles and mechanisms for guiding hybridization are also properly clarified.

Subjects

POROUS materials synthesis; ENERGY storage; HYBRID materials; POROUS materials; METAL-organic frameworks

Publication

Advanced Energy Materials, 2022, Vol 12, Issue 4, p1

ISSN

1614-6832

Publication type

Academic Journal

DOI

10.1002/aenm.202100321