Let G be the Euclidean motion group G = ℝ n ⋊ SO(n) realized as the semi-direct product of ℝ n and SO(n). Let K = SO(n) be a compact subgroup of G. The set of positive definite spherical functions on G is studied. Among other things, a result of Bochner which characterizes a K- bi-invariant positive definite spherical function in any locally compact group, is extended to the Gelfand pair (ℝ n ⋊ SO(n), SO(n) ).