Network flows and specifically water flow in open canals can be modeled by systems of balance laws defined on graphs. The shallow water or Saint-Venant system of balance laws is one of the most used model and present two phases: fluvial or sub-critical and torrential or super-critical. Phase transitions may occur within the same canal but transitions related to networks are less investigated. In this paper we provide a complete characterization of possible phase transitions for a case study of a simple scenario with two canals and one junction. However, our analysis allows the study of more complicate networks. Moreover, we provide some numerical simulations to show the theory at work.