Title: The Synthesis of Some Perhydrobenzimidazolinium Salts and Their Application in Pd-Carbene Catalyzed Heck and Suzuki Reactions.
Authors: Yiğit, Murat
Abstract: Novel 1,3-dialkylperhydrobenzimidazolinium chloride salts were prepared as precursors of N-heterocyclic carbenes 3a-e by reacting N,N'-dialkylcyclohexandiamine, triethyl orthoformate and ammonium chloride. The salts were characterized spectroscopically and the complexes formed in situ from Pd(OAc)2 and 3 have been tested as catalysts in homogenous Heck and Suzuki reactions.
Subjects: SALTS; PALLADIUM; CARBENES; AMMONIUM compounds; SPECTRUM analysis; IN situ hybridization; CATALYSTS; STYRENE; CATALYSIS
Publication: Molecules, 2009, Vol 14, Issue 6, p2032
ISSN: 1420-3049
Publication type: Academic Journal
DOI: 10.3390/molecules14062032

The Synthesis of Some Perhydrobenzimidazolinium Salts and Their Application in Pd-Carbene Catalyzed Heck and Suzuki Reactions.

Yiğit, Murat