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- Title
Tert-butyl hydroperoxide decomposition as a descriptor for liquid-phase hydrocarbon oxidation over transition metal oxide-based catalysts: a screening study.
- Authors
Büker, Julia; Shang, Jingqi; Angel, Steven; Budiyanto, Eko; Tüysüz, Harun; Wiggers, Hartmut; Schulz, Christof; Grünewald, Marcus; Baoxiang Peng; Muhler, Martin
- Abstract
Selective oxidation of hydrocarbons with environmentally friendly oxidizing agents is key to a sustainable future. Therefore, the development of heterogeneously catalyzed reactions using oxidants such as molecular oxygen and alkyl hydroperoxides is a promising approach. For the application of these oxidants on a large scale, highly active and selective catalysts must be developed, which requires a rapid screening of a large variety of materials. We report on a method that enables a volumetric quantification of the O2 amount evolved from the decomposition of alkyl hydroperoxides, which serves as a fast initial screening step for identifying effective catalysts for hydrocarbon oxidation reactions.
- Subjects
TRANSITION metal catalysts; OXIDIZING agents; HETEROGENEOUS catalysis; SUSTAINABILITY; OXIDATION; HYDROPEROXIDES
- Publication
ARKIVOC: Online Journal of Organic Chemistry, 2024, Vol 2024, p1
- ISSN
1551-7004
- Publication type
Academic Journal
- DOI
10.24820/ark.5550190.p012.158