Title: Effective one-pot synthesis of (E)-poly(vinyl arylenes) via trans-borylation/Suzuki coupling protocol.
Authors: Szyling, Jakub; Walkowiak, Jędrzej
Abstract: A new stereoselective method for the synthesis of (E)-poly(vinylarenes) on the basis of the Ru-H catalyzed trans-borylation reaction and sequential Suzuki coupling is described. Two different strategies of Pd-catalyzed polycondensation leading to unsaturated organic macromolecular compounds are discussed. Development of a one-pot procedure reduces costs and time, needed for the separation of intermediates, the amount of organic solvents used for purification and therefore has a positive influence on the process sustainability.
Subjects: CHEMICAL synthesis; BORYLATION; POLYCONDENSATION; ORGANIC solvents; ORGANOBORON compounds
Publication: Green Processing & Synthesis, 2017, Vol 6, Issue 3, p301
ISSN: 2191-9542
Publication type: Academic Journal
DOI: 10.1515/gps-2016-0217

Effective one-pot synthesis of (E)-poly(vinyl arylenes) via trans-borylation/Suzuki coupling protocol.

Szyling, Jakub; Walkowiak, Jędrzej