Consider the chiral non-Hermitian random matrix ensemble with parameters n and v, and let (ζ i) 1 ≤ i ≤ n be its n eigenvalues with positive x-coordinate. In this paper, we establish deviation probabilities and moderate deviation probabilities for the spectral radius (n n v) 1 2 max 1 ≤ i ≤ n | ζ i | 2 , as well as (n n v) 1 2 min 1 ≤ i ≤ n | ζ i | 2 .