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Title: Two new one-dimensional coordination polymers containing [N(CN)2]- - Syntheses, structures, and magnetic properties of [MII(3- Bzpy)2(N(CN)2)2] (M = Mn (1) and Co (2) and 3-Bzpy = 3-benzoylpyridine)
Authors: Bao, Qianqian; Ma, Yutao; Zhao, Qihua; Luo, Yanghui; Sun, Baiwang
Abstract: The structures of two one-dimensional coordination complexes, [MII(3-Bzpy)2(N(CN)2)2] (M = Mn ( 1) and Co ( 2) and 3-Bzpy = 3-benzoylpyridine), have been determined in this work. The two structures are isomorphous, crystallize in a monoclinic P21/ c space group, and show almost the same crystal structure. The magnetic measurements of the two compounds (2-300 K) indicate that antiferromagnetic exchanges exist between the metal ions of the two compounds.
Subjects: COORDINATION polymers synthesis; MAGNETIC properties; COORDINATION compounds; CRYSTAL structure; ANTIFERROMAGNETISM; METAL ions
Publication: Canadian Journal of Chemistry, 2012, Vol 90, Issue 4, p362
ISSN: 0008-4042
Publication type: Academic Journal
DOI: 10.1139/v2012-004

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Two new one-dimensional coordination polymers containing [N(CN)<sub>2</sub>]<sup>-</sup> - Syntheses, structures, and magnetic properties of [M<sup>II</sup>(3- Bzpy)<sub>2</sub>(N(CN)<sub>2</sub>)<sub>2</sub>] (M = Mn (1) and Co (2) and 3-Bzpy = 3-benzoylpyridine)