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Title

Thermal behavior of layered perovskite-like compounds in the Bi<sub>4</sub>Ti<sub>3</sub>O<sub>12</sub>-BiFeO<sub>3</sub> system.

Authors

N. Lomanova; V. Ugolkov; V. Gusarov

Abstract

Abstract  The thermal properties of compounds of the general formula Bi m 1 Fe m − 3 Ti3O3m 3, which are layered perovskite-like phases of the Aurivillius type, are investigated as a function of their composition. It is demonstrated that the temperature of decomposition of the Bi m 1 Fe m − 3 Ti3O3m 3 compounds decreases with an increase in the thickness of perovskite-like layers alternating in the structure and that the composition dependence of the temperature of the structural transition observed in these compounds exhibits a more complex behavior. The linear thermal expansion coefficients of all the compounds under investigation are found to be virtually independent of the composition.

Subjects

OXIDE minerals; PEROVSKITE; THERMAL properties; THERMAL expansion

Publication

Glass Physics & Chemistry, 2007, Vol 33, Issue 6, p608

ISSN

1087-6596

Publication type

Academic Journal

DOI

10.1134/S1087659607060120

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