Title: Alternative Synthetic Routes to Dioxolanes and Thiadiazines.
Authors: Isobaev, M. D.; Pulatov, E. Kh.; Abdullaev, T. Kh.; Turdialiev, M. Z.; Mavlonov, B. G.; Jumaeva, M. I.
Abstract: The hydrolysis of 2-methylbut-3-yn-2-yl carbamate gave 4,4-dimethyl-5-methylidene-1,3-dioxo-lan-2-one, whereas 2-methylbut-3-yn-2-ol was converted under similar conditions to 3-hydroxy-3-methylbutan-2-one. 2-[2-Amino(hydrazinyl)-6H-1,3,4-thiadiazin-5-yl]propan-2-yl carbamates were synthesized by reacting 4-bromo-2-methyl-3-oxobutan-2-yl carbamate with thiosemicarbazide and carbonothioic dihydrazide, respectively.
Subjects: DIOXOLANES; ACETYLENE derivatives; CARBAMATES; HYDROLYSIS; HYDROGEN bonding; THIADIAZOLES; THIOSEMICARBAZONES
Publication: Russian Journal of Organic Chemistry, 2021, Vol 57, Issue 3, p369
ISSN: 1070-4280
Publication type: Academic Journal
DOI: 10.1134/S1070428021030076

Alternative Synthetic Routes to Dioxolanes and Thiadiazines.

Isobaev, M. D.; Pulatov, E. Kh.; Abdullaev, T. Kh.; Turdialiev, M. Z.; Mavlonov, B. G.; Jumaeva, M. I.