Title: Mechanism of the reaction of 3,3-dimethyl-1-trimethylsilyl-2-trimethylsiloxy-1-phosphabut-1-ene with chlorobis( o-phenylenedioxy)phosphorane.
Authors: Ishmaeva, E.; Chachkov, D.; Alimova, A.; Vereshchagina, Ya.
Abstract: The article discusses the mechanism of the reaction of 3,3-dimethyl-1-trimethylsilyl-2-trimethylsiloxy-1-phosphabut-1-ene with chlorobis( o-phenylenedioxy)phosphorane. The study has used the quantum chemical methods in examining the mechanism of the reaction. It also localized transition state for the transformation of the E isomer into Z isomer.
Subjects: ISOMERASES; ISOMERS; ETHANES; CHEMICAL reactions; ORGANIC chemistry
Publication: Russian Journal of Organic Chemistry, 2014, Vol 50, Issue 4, p608
ISSN: 1070-4280
Publication type: Academic Journal
DOI: 10.1134/S1070428014040307

Mechanism of the reaction of 3,3-dimethyl-1-trimethylsilyl-2-trimethylsiloxy-1-phosphabut-1-ene with chlorobis( o-phenylenedioxy)phosphorane.

Ishmaeva, E.; Chachkov, D.; Alimova, A.; Vereshchagina, Ya.