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- Title
Mechanism of the reaction of 3,3-dimethyl-1-trimethylsilyl-2-trimethylsiloxy-1-phosphabut-1-ene with chlorobis( o-phenylenedioxy)phosphorane.
- Authors
Ishmaeva, E.; Chachkov, D.; Alimova, A.; Vereshchagina, Ya.
- Abstract
The article discusses the mechanism of the reaction of 3,3-dimethyl-1-trimethylsilyl-2-trimethylsiloxy-1-phosphabut-1-ene with chlorobis( o-phenylenedioxy)phosphorane. The study has used the quantum chemical methods in examining the mechanism of the reaction. It also localized transition state for the transformation of the E isomer into Z isomer.
- Subjects
ISOMERASES; ISOMERS; ETHANES; CHEMICAL reactions; ORGANIC chemistry
- Publication
Russian Journal of Organic Chemistry, 2014, Vol 50, Issue 4, p608
- ISSN
1070-4280
- Publication type
Academic Journal
- DOI
10.1134/S1070428014040307