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- Title
Chemoselectivity of the reaction of 2-chloro-4(5)-(dichlorophosphoryloxy)-1,3,2-benzodioxaphosphole 2-oxides with phosphorus pentachloride.
- Authors
Nasibullin, I.; Nemtarev, A.; Mironov, V.
- Abstract
The article discusses a study on the chemoselectivity of the reaction of 2-chloro-4(5)-(dichlorophosphoryloxy)-1,3,2-benzodioxaphosphole 2-oxides with phosphorus pentachloride. The study explores the reaction of cyclic chlorophosphates VII and VIII with an equimolar amount of phosphorus pentachloride in methylene chloride. Also tackled is the phosphorus atoms in the resulting 2,2,2-trichloro-4(5)-(dichlorophosphoryloxy)- 1,3,2?5-benzodioxaphospholes.
- Subjects
PHOSPHORAMIDES; PHOSPHORANE; PHOSPHORUS compounds; PHOSPHINES; PHOSPHINE oxides
- Publication
Russian Journal of Organic Chemistry, 2014, Vol 50, Issue 4, p603
- ISSN
1070-4280
- Publication type
Academic Journal
- DOI
10.1134/S1070428014040289