Title: Synthesis of polypyrrole intercalated into channels of nanoporous metal-organic coordination polymer.
Authors: Aliev, S.; Maksimovskii, E.; Samsonenko, D.; Dybtsev, D.; Fedin, V.
Abstract: A procedure has been developed for the intercalation of pyrrole into nanocavities of a metal-organic coordination polymer, chromium terephthalate MIL-101, and oxidative polymerization of pyrrole has been accomplished. The new composite nanomaterial thus obtained, polypyrrole@MIL-101, has been characterized by the data of elemental analysis, X-ray powder diffraction, thermal analysis, and scanning electron microscopy. Its specific surface area has been estimated at 1700 m/g according to Brunauer-Emmett-Teller.
Subjects: PYRROLES; NANOPOROUS materials; NANOSTRUCTURED materials; POROUS semiconductors; CHROMIUM; X-ray diffraction
Publication: Russian Journal of Organic Chemistry, 2014, Vol 50, Issue 4, p510
ISSN: 1070-4280
Publication type: Academic Journal
DOI: 10.1134/S1070428014040113

Synthesis of polypyrrole intercalated into channels of nanoporous metal-organic coordination polymer.

Aliev, S.; Maksimovskii, E.; Samsonenko, D.; Dybtsev, D.; Fedin, V.