Title: Effect of pressure on the rate of the Diels-Alder reaction of diethyl azodicarboxylate with 9,10-dimethylanthracene.
Authors: Kiselev, V.; Kornilov, D.; Kashaeva, E.; Potapova, L.; Konovalov, A.
Abstract: The enthalpy, entropy, and volume of activation and volume of the Diels-Alder reaction of diethyl azodicarboxylate with 9,10-dimethylanthracene in 1,2-dichloroethane have been determined. Possible factors responsible for the sharp difference between the volumes of activation and reaction are considered.
Subjects: ENTHALPY; DIELS-Alder reaction; CHEMICAL reactions; DIENOPHILES; ORGANIC chemistry
Publication: Russian Journal of Organic Chemistry, 2014, Vol 50, Issue 4, p489
ISSN: 1070-4280
Publication type: Academic Journal
DOI: 10.1134/S1070428014040071

Effect of pressure on the rate of the Diels-Alder reaction of diethyl azodicarboxylate with 9,10-dimethylanthracene.

Kiselev, V.; Kornilov, D.; Kashaeva, E.; Potapova, L.; Konovalov, A.