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- Title
Synthesis of 2,6-diazatricyclododecanes from 2-hydroxy-3,5-dinitropyridine.
- Authors
Morozova, E.; Yakunina, I.; Blokhin, I.; Shakhkel'dyan, I.; Atroshchenko, Yu.
- Abstract
The article presents a study on the transformation of 2-hydroxy-3,5-dinitropyridine into tricyclic bispidine derivatives via nucleophilic addition of acetone carbodianion and double Mannich condensation. The study used 2-Hydroxy-3,5-dinitropyridine that was synthesized by nitration of 2-hydroxypyridine. treatment of 2-hydroxy-3,5-dinitropyridine (I) in acetone leads to the formation of 6-substituted 4,8-dinitro-2,6- diazatricyclo[6.4.0.04,9]dodecane-3,11-diones IIIa and IIIb.
- Subjects
HYDROXY acids; NUCLEOPHILIC addition (Chemistry); ACETONE; CONDENSATION; CHEMICAL synthesis; NITRATION; HYDROXYPYRIDINES
- Publication
Russian Journal of Organic Chemistry, 2012, Vol 48, Issue 10, p1384
- ISSN
1070-4280
- Publication type
Academic Journal
- DOI
10.1134/S1070428012100235