Title: Synthesis of unsymmetrical phosphorus-containing macrocycles on the basis of hydroquinone, 4,4′-(propane-2,2-diyl)diphenol, and resorcinol.
Authors: Blokhin, Yu. I.; Kornilov, K. N.; Volchenkova, Yu. V.
Abstract: Bisphosphorylation of hydroquinone and 4,4′-(propane-2,2-diyl)diphenol was performed for the first time in ethyl acetate. The bisphosphorylated products were used in molecular assembly of unsymmetrical phosphorus(III)-containing macrocycles consisting of hydroquinone and 2,2-bis( p-hydroxyphenyl)propane or resorcinol fragments. The macrocyclic compound based on hydroquinone and 2,2-bis( p-hydroxyphenyl)-propane was subjected to oxidation and sulfurization to obtain the corresponding phosphorus(V) derivatives. Its biological activity was also studied.
Subjects: MACROCYCLIC compounds; HYDROQUINONE; RESORCINOL; ACETATES; PHOSPHORUS
Publication: Russian Journal of Organic Chemistry, 2009, Vol 45, Issue 6, p900
ISSN: 1070-4280
Publication type: Academic Journal
DOI: 10.1134/S1070428009060177

Synthesis of unsymmetrical phosphorus-containing macrocycles on the basis of hydroquinone, 4,4′-(propane-2,2-diyl)diphenol, and resorcinol.

Blokhin, Yu. I.; Kornilov, K. N.; Volchenkova, Yu. V.