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- Title
Aqueous solutions of geminal alkylammonium surfactants as a medium for reactions of long-chain amines.
- Authors
Mirgorodskaya, A. B.; Kudryavtseva, L. A.
- Abstract
The formation of surfactant-hydrophobic amine mixed aggregates reduces the p Ka of long-chain amines by 1–1.5 units compared with those in molecular solutions and is an important factor responsible for the high catalytic effect of the system in ester bond cleavage. In aqueous solution of geminal surfactants, the rate of azomethine formation in the reaction of long-chain amines with benzaldehydes is an order-of-magnitude higher than in ethanol.
- Subjects
SURFACE active agents; ORGANIC compounds; AMINES; CHEMICAL reactions; ETHANOLAMINES; CATALYSTS
- Publication
Russian Journal of General Chemistry, 2009, Vol 79, Issue 1, p42
- ISSN
1070-3632
- Publication type
Academic Journal
- DOI
10.1134/S1070363209010071