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- Title
Geminal alkylammonium surfactants: Aggregation properties and catalytic activity.
- Authors
Mirgorodskaya, A. B.; Kudryavtseva, L. A.; Pankratov, V. A.; Lukashenko, S. S.; Rizvanova, L. Z.; Konovalov, A. I.
- Abstract
Geminal alkylammonium surfactants containing a hexamethylene spacer show a specific behavior, namely, a catalytic effect at low concentrations of the detergent in the system. The critical micellization concentrations of these surfactants are by an order of magnitude lower than those of the related surfactants with one hydrophobic fragment. The effect exerted on the hydrolysis of carboxylic acid esters by micellar structural rearrangements induced by addition of a supporting electrolyte is determined.
- Subjects
SURFACE active agents; CATALYSIS; AZEPINES; HYDROLYSIS; CARBOXYLIC acids; ELECTROLYTES
- Publication
Russian Journal of General Chemistry, 2006, Vol 76, Issue 10, p1625
- ISSN
1070-3632
- Publication type
Academic Journal
- DOI
10.1134/S1070363206100215