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Title

Synthesis and X-ray diffraction study of [UO(NO)(HO)] · 2CHO.

Authors

Serezhkina, L.; Vologzhanina, A.; Klynin, E.; Korlyukov, A.; Moiseev, I.; Serezhkin, V.

Abstract

The compound [UO(NO)(HO)] · 2CHO was synthesized and studied by IR spectroscopy and X-ray diffraction. The structure consists of the neutral island groups [UO(NO)(HO)], which belong to the crystal-chemical group AB M ( A = UO, B = NO, M = HO) of uranyl complexes, and 1-adamantyl methyl ketone molecules. The characteristic features of the association of the complexes [UO(NO)(HO)] and 1-adamantyl methyl ketone molecules in the crystal structure via hydrogen bonds are considered with the use of Voronoi-Dirichlet polyhedra.

Subjects

X-ray diffraction; INFRARED spectra; CRYSTAL structure; METHYL ketones; HYDROGEN bonding; POLYHEDRA

Publication

Crystallography Reports, 2012, Vol 57, Issue 2, p252

ISSN

1063-7745

Publication type

Academic Journal

DOI

10.1134/S1063774512020186

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