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Title

Lead (II) selenite halides Pb(SeO) X ( X = Br, I): Synthesis and crystal structure.

Authors

Berdonosov, P.; Olenev, A.; Dolgikh, V.

Abstract

Two lead selenite halides, Pb(SeO)Br and Pb(SeO)I, have been prepared by solid-phase synthesis and structurally characterized. These compounds are isotypic and can be considered 3D with a microporous framework composed of lead polyhedra (distorted Archimedean antiprisms formed by oxygen and halogen atoms). The framework contains channels oriented in the [010] direction. These channels contain selenium atoms, which are bound with framework oxygen atoms belonging to different lead polyhedra.

Subjects

LEAD selenide crystals; HALIDES; CRYSTAL structure; INORGANIC synthesis; POROUS materials; POLYHEDRA

Publication

Crystallography Reports, 2012, Vol 57, Issue 2, p200

ISSN

1063-7745

Publication type

Academic Journal

DOI

10.1134/S1063774512020034

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