It is established that the two-dimensional crystallization of sodium chloride on the surface of a biopolymer film (film of a glycoprotein, mucin), which is used as a template, gives rise to the formation of crystals with unusual morphology-in particular, dendrites. This type of crystallization is observed in two cases-namely, when drying a film formed from a salt-containing mucin dispersion and when drying a salt solution droplet on the surface of a dry mucin film obtained from a salt-free mucin dispersion. Mechanisms leading to unusual salt crystallization are discussed, and the role of specific interactions of sodium chloride with mucin is shown.