The effect of MgO on the optical properties of lithium sodium borate doped with Cu ions.

Alajerami, Yasser; Hashim, Suhairul; Hassan, Wan; Ramli, Ahmad; Saleh, Muneer

The current work presented the photoluminescence (PL) properties of a new glass system, which are reported for the first time. Based on the attractive properties of borate glass, a mixture of boric acid (70-x mol %) modified with lithium (20 mol %) and sodium carbonate (10 mol %) was prepared. The current study illustrated the effect of dopant and co-dopant techniques on the lithium sodium borate (LNB). Firstly, 0.1 mol % of copper ions doped with LNB was excited at 610 nm. The emission spectrum showed two prominent peaks in the violet region (403 and 440 nm). Then, we remarked the effect of adding different concentration of MgO on the optical properties of LNB. The results showed the great effect of magnesium oxide on the PL intensities (enhanced more than two times). Moreover, an obvious shifting has been defined toward the blue region (440 → 475 nm). The up-conversion optical properties were observed in all emission spectra. This enhancement is contributed to the energy transfer from MgO ions to monovalent Cu ion. It is well known that magnesium oxide alone generates weak emission intensity, but during this increment the MgO act as an activator (co-doped) for Cu ions. Finally, energy band gap, density, ion concentration, molar volume, Polaron radius and inter-nuclear distance all were measured for the current samples. The current samples were subjected to XRD for amorphous confirmation and IR for glass characterization before and after dopants addition. Finally, some of significant physical and optical parameters were also calculated.

MAGNESIUM oxide; OPTICAL properties of metals; LITHIUM borate; DOPING agents (Chemistry); COPPER ions; PHOTOLUMINESCENCE; MIXTURES; SODIUM aluminate

Optics & Spectroscopy, 2013, Vol 114, Issue 4, p537

0030-400X

Academic Journal

10.1134/S0030400X1304022X