Title: FIRST EXAMPLES OF MOLECULAR POLYCHALCOGENIDE COMPLEXES OF THULIUM.
Authors: Demkin, A. G.; Savkov, B. Yu.; Sukhikh, T. S.; Konchenko, S. N.
Abstract: Two new polychalcogenide complexes of thulium are obtained by the interaction of (Cp′′′ = 1,3,4-tris(tert-butyl)cyclopentadienide) (1) with elemental sulfur under different conditions: (2) and (18-cr-6 – 1,4,7,10,13,16-hexaoxa cyclooctadecane) (3). A reaction of complex 2 with CS2 in toluene is studied. It results in compound (4) that is the first example of Tm(III) perthiocarbonate complex. Structures of 2-4 are determined by single crystal X-ray diffraction.
Subjects: SINGLE crystals; THULIUM; X-ray diffraction; COORDINATION compounds; RARE earth metals; SULFUR; THIADIAZOLES
Publication: Journal of Structural Chemistry, 2021, Vol 62, Issue 6, p957
ISSN: 0022-4766
Publication type: Academic Journal
DOI: 10.1134/S0022476621060159

FIRST EXAMPLES OF MOLECULAR POLYCHALCOGENIDE COMPLEXES OF THULIUM.

Demkin, A. G.; Savkov, B. Yu.; Sukhikh, T. S.; Konchenko, S. N.