Title: Identification of the Structure of Polybutadiene Terminal Units by NMR Spectroscopy with T2-Filter.
Authors: Rozentsvet, V. A.; Sablina, N. A.; Ulyanova, D. M.; Tolstoy, P. M.; Smirnov, S. N.; Novakov, I. A.
Abstract: A new method for the identification of the structure of terminal units in polybutadiene synthesized by cationic polymerization has been developed. The method consists of conducting T2-filtered NMR experiments, which make it possible to reduce the intensities of the spectral signals of the main-chain carbon atoms and significantly increase the intensities of the signals of the carbon atoms in the head and end polybutadiene units characterized by higher mobility.
Subjects: NUCLEAR magnetic resonance spectroscopy; POLYBUTADIENE; ADDITION polymerization; RADIANT intensity; IDENTIFICATION
Publication: Doklady Physical Chemistry, 2020, Vol 491, Issue 2, p40
ISSN: 0012-5016
Publication type: Academic Journal
DOI: 10.1134/S0012501620040028

Identification of the Structure of Polybutadiene Terminal Units by NMR Spectroscopy with T2-Filter.

Rozentsvet, V. A.; Sablina, N. A.; Ulyanova, D. M.; Tolstoy, P. M.; Smirnov, S. N.; Novakov, I. A.