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- Title
Molecular Binding of α-Cyclodextrin with 1,4-Dioxane in the Solid State.
- Authors
Ceborska, Magdalena
- Abstract
The inclusion of 1,4-dioxane in α-cyclodextrin has been studied by X-ray crystallography. The stoichiometric ratio of the host–guest complex, which showed the formation of a head-to-head dimer of the host stabilized by a net of hydrogen bonds, was found to be 2:3. Two 1,4-dioxane molecules are located inside the cavities of the α-cyclodextrin dimer, whereas the third guest molecule is found in the interstitial space between two head-to-head cyclodextrin molecules.
- Subjects
CYCLODEXTRINS; DIOXANE; SOLID state chemistry; DIMERS; STOICHIOMETRY; X-ray crystallography; INCLUSION compounds; HYDROGEN bonding
- Publication
Journal of Carbohydrate Chemistry, 2014, Vol 33, Issue 1, p48
- ISSN
0732-8303
- Publication type
Academic Journal
- DOI
10.1080/07328303.2013.875555