Stereochemistry of heterometallic platinum clusters.

Melnik, M.; Garaj, J.; Holloway, C.E.

Heterometallic platinum complexes cover a huge field, as shown by a recent survey covering the crystallographic and structural data of almost 1500 examples. About 5% of those complexes exists as isomers and are summarized in this review; except one cis-trans example, the remainder are distortion isomers. These are discussed in terms of the coordination about the platinum atom, and correlations are drawn between donor atom, bond lengths and interbond angles, with attention to trans effect and metal-metal bonds. Distortion isomers, differing only by degree of distortion in Pt-L and Pt-M distances and L-M-L bond angles, spread over a wide range of oxidation states of platinum: zero, +1, +2 (most common) and +4. The mean Pt-Pt bond distance elongate with increase in oxidation state of platinum: 2.705 Å (Pt(0)-Pt(0)) < 2.720 Å (Pt(I)-Pt(I)) < 2.773 Å (Pt(II)-Pt(II)). The shortest mean Pt-M bond distances are: Pt(0)-Ga = 2.37 Å; Pt(I) = Au 2.697 Å, Pt(II)-Fe = 2.625 Å and Pt(IV)-Sn, 2.580 Å.

STEREOCHEMISTRY; PLATINUM; CHEMICAL structure; PLATINUM group; TRANSITION metals

Journal of Coordination Chemistry, 2008, Vol 61, Issue 19, p3021

0095-8972

Academic Journal

10.1080/00958970802010591