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Title

Dielectric study of acrylonitrile-1,4-dioxane mixtures using a Time Domain Reflectometry.

Authors

Dongre, D.G.; Gubre, A.G.; Garad, N.P.; Saknure, S.H.; Kumbharkhane, A.C.

Abstract

The frequency-dependent complex permittivity spectra (CPS) of the acrylonitrile (ACRN) and 1,4-dioxane (DX) binary mixture in the range from 10 MHz to 30 GHz were measured using the time domain reflectometry (TDR) technique. Experimentally obtained CPS was fitted into the Debye equation. Dielectric relaxation behaviours depend on the temperature and concentration of binary mixtures. The obtained dielectric parameters, the Kirkwood correlation, and the Bruggeman factor have been discussed to understand the molecular association and hydrogen bonding interactions in the mixture.

Subjects

DIELECTRIC relaxation; HYDROGEN bonding interactions; BINARY mixtures; PERMITTIVITY; REFLECTOMETRY

Publication

Physics & Chemistry of Liquids, 2025, Vol 63, Issue 1, p13

ISSN

0031-9104

Publication type

Academic Journal

DOI

10.1080/00319104.2024.2349029

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