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Title: Catalytic Effect of Reverse Micelles of a Cationic Surfactant on the Reaction of Calix[4]resorcinolarenes with 4-Nitrophenyl Bis(chloromethyl)phosphinate.
Authors: Zhil'tsova, E. P.; Kudryavtseva, L. A.; Timosheva, A. P.; Kharitonov, N. I.; Konovalov, A. I.
Abstract: The presence of the aminomethyl fragment in the calix[4]resorcinolarene molecule favors its phosphorylation in chloroform. Reverse micelles of (2-hydroxyethyl)dimethylpentadecylammonium bromide catalyze this reaction, the catalytic effect being dependent on the length of the hydrocarbon chain of a calixarene and detergent concentration.
Subjects: CATALYSTS; REVERSED micelles; SURFACE active agents; CHLOROMETHYL group; PHOSPHORYLATION; CHLOROFORM; CHEMICAL inhibitors
Publication: Russian Journal of General Chemistry, 2004, Vol 74, Issue 4, p627
ISSN: 1070-3632
Publication type: Academic Journal
DOI: 10.1023/B:RUGC.0000031870.38538.3d

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Catalytic Effect of Reverse Micelles of a Cationic Surfactant on the Reaction of Calix[4]resorcinolarenes with 4-Nitrophenyl Bis(chloromethyl)phosphinate.