Title: Effect of the composition of the reaction mixture on the preparation of L-cysteine-stabilized CdS nanoparticles and their optical properties.
Authors: Krupko, E.; Grodzyuk, G.; Khalavka, Yu.; Okrepka, G.; Shcherbak, L.
Abstract: A study was carried out on the dependence of the optical properties such as the maxima in the absorption and luminescence spectra, Stokes shift, and quantum yield on the composition of the three-component Cd-L-Cys-S reaction system under synthesis conditions at 298 ± 2 K and pH 7. Equations describing the dependence of the position of the maximum in the luminescence and absorption spectra of solutions on their composition were obtained by mathematical planning using the Scheffe simplex-lattice design and treatment of the data. The region of compositions for unstable colloidal solutions was determined.
Subjects: CADMIUM sulfide; MIXTURES; CHEMICAL reactions; NANOPARTICLES; OPTICAL properties of metals; SOLUTION (Chemistry); LUMINESCENCE spectroscopy; ABSORPTION spectra; QUANTUM chemistry
Publication: Theoretical & Experimental Chemistry, 2011, Vol 47, Issue 2, p101
ISSN: 0040-5760
Publication type: Academic Journal
DOI: 10.1007/s11237-011-9189-7

Effect of the composition of the reaction mixture on the preparation of L-cysteine-stabilized CdS nanoparticles and their optical properties.

Krupko, E.; Grodzyuk, G.; Khalavka, Yu.; Okrepka, G.; Shcherbak, L.