Title: Phosphorylation of Pyrimidinophane in the Reversed Micellar Solutions of Cationic and Nonionogenic Surfactants.
Authors: Zhil'tsova, E.; Kudryavtseva, L.; Gainanova, G.; Timosheva, A.; Mikhailov, A.; Giniyatullin, R.; Nafikova, A.; Reznik, V.; Konovalov, A.
Abstract: Reactions of a macrocycle containing three pyrimidine fragments and N,N′-bis(2-methylthio-6-methylpyrimidin-4-yl)-hexamethylenediamine with p-nitrophenyl bis(chloromethyl)phosphinate in the micellar solutions of cetyltrimethylammonium bromide, polyethyleneglycol-600 laurate and their mixture in chloroform was investigated spectrophotometrically. Catalytic activity of micelles depends on their structure, concentration of surfactants, molar fraction of the latter in solution, and structure of the nucleophilic reagent.
Subjects: MACROCYCLIC compounds; MACROMOLECULES; PYRIMIDINES; HETEROCYCLIC compounds; POLYETHYLENE; ETHYLENE
Publication: Russian Journal of General Chemistry, 2005, Vol 75, Issue 11, p1729
ISSN: 1070-3632
Publication type: Academic Journal
DOI: 10.1007/s11176-005-0501-x

Phosphorylation of Pyrimidinophane in the Reversed Micellar Solutions of Cationic and Nonionogenic Surfactants.

Zhil'tsova, E.; Kudryavtseva, L.; Gainanova, G.; Timosheva, A.; Mikhailov, A.; Giniyatullin, R.; Nafikova, A.; Reznik, V.; Konovalov, A.