Title: Influence of packing of the reactants and products in solution on the volume parameters of the Diels-Alder reaction.
Authors: Kiselev, V. D.; Kashaeva, E. A.; Potapova, L. N.; Shikhab, M. S.; Konovalov, A. I.
Abstract: The possible causes of a dramatic difference in the volume parameters (by up to 15-20 cm3 mol-1) of the Diels-Alder reactions involving bulky and small reactants are discussed. The partial molar volumes of anthracene and 9,10-dihydroanthracene and the heats of their solution in six solvents were determined.
Subjects: DIELS-Alder reaction; CHEMICAL reactions; ALDER; POLYCYCLIC aromatic hydrocarbons; SOLUTION (Chemistry); SOLVENTS
Publication: Russian Journal of General Chemistry, 2004, Vol 74, Issue 10, p1552
ISSN: 1070-3632
Publication type: Academic Journal
DOI: 10.1007/s11176-005-0054-z

Influence of packing of the reactants and products in solution on the volume parameters of the Diels-Alder reaction.

Kiselev, V. D.; Kashaeva, E. A.; Potapova, L. N.; Shikhab, M. S.; Konovalov, A. I.