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- Title
Influence of packing of the reactants and products in solution on the volume parameters of the Diels-Alder reaction.
- Authors
Kiselev, V. D.; Kashaeva, E. A.; Potapova, L. N.; Shikhab, M. S.; Konovalov, A. I.
- Abstract
The possible causes of a dramatic difference in the volume parameters (by up to 15-20 cm3 mol-1) of the Diels-Alder reactions involving bulky and small reactants are discussed. The partial molar volumes of anthracene and 9,10-dihydroanthracene and the heats of their solution in six solvents were determined.
- Subjects
DIELS-Alder reaction; CHEMICAL reactions; ALDER; POLYCYCLIC aromatic hydrocarbons; SOLUTION (Chemistry); SOLVENTS
- Publication
Russian Journal of General Chemistry, 2004, Vol 74, Issue 10, p1552
- ISSN
1070-3632
- Publication type
Academic Journal
- DOI
10.1007/s11176-005-0054-z